Perovskite Na0.5Bi0.5TiO3: a potential family of peculiar lead-free electrostrictors
文献类型：期刊论文
| 作者 | Yin, J; Liu, G; Zhao, CL; Huang, YL; Li, ZT; Zhang, XM; Wang, K; Wu, JG |
| 刊名 | JOURNAL OF MATERIALS CHEMISTRY A
 |
| 出版日期 | 2019 |
| 卷号 | 7期号:22页码:13658—13670 |
| 关键词 | ULTRA-LOW HYSTERESIS PHASE-TRANSITIONS ELECTRIC-FIELD STRAIN TEM COEFFICIENT DENSITY |
| ISSN号 | 2050-7488 |
| DOI | 10.1039/c9ta03140e |
| 文献子类 | 期刊论文 |
| 英文摘要 | For perovskite ferroelectric oxides, the composition-induced transition from ferroelectrics to relaxors can enhance their electrostrictive coefficient Q(33) remarkably, and has been attracting more and more attention in recent years. Achieving a larger electro-strain response is one of the most original driving forces for pursuing higher Q(33) values, while the two are often incompatible. Herein, taking the promising relaxor ferroelectric Na0.5Bi0.5TiO3 (NBT) as the research object, we report the excellent electrostriction-like electro-strain behaviors (0.41% <= S-uni <= 0.46%, 25 <= T <= 125 degrees C; S-uni exhibits only 2.23% decline after 105 cycles) together with a series of enhanced Q(33) values (0.029-0.047 m(4) C-2). Accompanied by the reconstruction of de-coupled A-O interactions, the electric-field-induced relaxor to ferroelectric state transition contributes to the superior electro-strain behaviors, while the enhanced Q(33) will greatly degenerate during this transition process. In contrast to the non-hysteretic electrostriction observed in linear dielectrics, for NBT-based relaxor ferroelectrics, the peculiar coexistence of ferroelectric in-phase a(0)a(0)c(+) and anti-phase a(-)a(-)a(-) tiltings is suggested to contribute to the enhanced electrostriction-like behaviors observed in this work. These observations indicate that NBT-based systems can be considered as a potential family of peculiar lead-free electrostrictors for application in the field of actuators. |
| 语种 | 英语 |
| 源URL | [http://ir.sinap.ac.cn/handle/331007/31754]  |
| 专题 | 上海应用物理研究所_中科院上海应用物理研究所2011-2017年 |
| 作者单位 | 1.Tsinghua Univ, Sch Mat Sci & Engn, Beijing 100084, Peoples R China; 2.Sichuan Univ, Dept Mat Sci, Chengdu 610064, Sichuan, Peoples R China; 3.Chinese Acad Sci, Shanghai Inst Appl Phys, Shanghai Synchrotron Radiat Facil, Pudong New Area, Shanghai 201204, Peoples R China |
| 推荐引用方式 GB/T 7714 | Yin, J,Liu, G,Zhao, CL,et al. Perovskite Na0.5Bi0.5TiO3: a potential family of peculiar lead-free electrostrictors[J]. JOURNAL OF MATERIALS CHEMISTRY A,2019,7(22):13658—13670. |
| APA | Yin, J.,Liu, G.,Zhao, CL.,Huang, YL.,Li, ZT.,...&Wu, JG.(2019).Perovskite Na0.5Bi0.5TiO3: a potential family of peculiar lead-free electrostrictors.JOURNAL OF MATERIALS CHEMISTRY A,7(22),13658—13670. |
| MLA | Yin, J,et al."Perovskite Na0.5Bi0.5TiO3: a potential family of peculiar lead-free electrostrictors".JOURNAL OF MATERIALS CHEMISTRY A 7.22(2019):13658—13670. |
入库方式： OAI收割
来源：上海应用物理研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。