The oxidation of UF4 in FLiNaK melt and its electrolysis
文献类型：期刊论文
| 作者 | Han, D; She, CF; Niu, YS; Yang, X; Geng, JX; Cui, RR; Sun, LX; Hu, CW; Liu, YY; Su, T |
| 刊名 | JOURNAL OF RADIOANALYTICAL AND NUCLEAR CHEMISTRY
 |
| 出版日期 | 2019 |
| 卷号 | 319期号:3页码:899—906 |
| 关键词 | MOLTEN-SALT REACTOR URANIUM SPECTRA |
| ISSN号 | 0236-5731 |
| DOI | 10.1007/s10967-019-06416-w |
| 文献子类 | 期刊论文 |
| 英文摘要 | The oxidation of UF4 in LiF-NaF-KF (FLiNaK) melt with oxygen sparging was conducted at 823K and analyzed by in situ infrared spectrometer, UV-Vis absorption spectrometer, and other characterizations with thermodynamic calculations, indicating UF4 was converted to UO2F2 with the following reaction mechanism: 2UF(4) (l)+O-2(g)+2H(2)O(g)=2UO(2)F(2)(l)+4HF(g). Cyclic voltammetry measurements showed that the reduction of UO22+ in oxidized melt exhibited two steps both with one exchanged electron: UO22++e(-)UO(2)(+) and UO2++e(-)UO(2). By potentiostatic electrolysis, the product of UO2 was obtained with nanoscale triangular sheet structure. |
| 语种 | 英语 |
| 源URL | [http://ir.sinap.ac.cn/handle/331007/31859]  |
| 专题 | 上海应用物理研究所_中科院上海应用物理研究所2011-2017年 |
| 作者单位 | 1.Chinese Acad Sci, Shanghai Inst Appl Phys, Shanghai 201800, Peoples R China; 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China; 3.Chinese Acad Sci, Ctr Excellence TMSR Energy Syst, Shanghai 201800, Peoples R China |
| 推荐引用方式 GB/T 7714 | Han, D,She, CF,Niu, YS,et al. The oxidation of UF4 in FLiNaK melt and its electrolysis[J]. JOURNAL OF RADIOANALYTICAL AND NUCLEAR CHEMISTRY,2019,319(3):899—906. |
| APA | Han, D.,She, CF.,Niu, YS.,Yang, X.,Geng, JX.,...&Li, QN.(2019).The oxidation of UF4 in FLiNaK melt and its electrolysis.JOURNAL OF RADIOANALYTICAL AND NUCLEAR CHEMISTRY,319(3),899—906. |
| MLA | Han, D,et al."The oxidation of UF4 in FLiNaK melt and its electrolysis".JOURNAL OF RADIOANALYTICAL AND NUCLEAR CHEMISTRY 319.3(2019):899—906. |
入库方式： OAI收割
来源：上海应用物理研究所
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