Thermoplastic shape memory composites with enhanced recovery stress and recovery ratio based on double roles of PVAc-g-GO
文献类型：期刊论文
| 作者 | Zhao, JX; Li, JY; Li, YJ; You, JC |
| 刊名 | COMPOSITES COMMUNICATIONS
 |
| 出版日期 | 2019 |
| 卷号 | 13期号:-页码:52—56 |
| 关键词 | ACID)/GRAPHENE OXIDE NANOCOMPOSITES GRAPHENE OXIDE CRYSTALLIZATION NANOPLATELETS COPOLYMERS BEHAVIOR PERFORMANCE |
| ISSN号 | 2452-2139 |
| DOI | 10.1016/j.coco.2019.02.009 |
| 文献子类 | 期刊论文 |
| 英文摘要 | The fabrication of thermoplastic shape memory PLLA-based composites based on simultaneous "shape fixed phase role" and "reinforcement phase role" of nanofillers, corresponding to better performance and higher productivity, remains as a great challenge. In this work, polyvinyl acetate grafted GO (PVAc-g-GO) has been employed to prepare shape memory PLLA/PVAc-g-GO composite based on the good miscibility between PLLA and PVAc. The physical entanglement between them produces thermoplastic shape memory composites. Furthermore, the modified GO plays double roles in shape memory performance. On one hand, it can depress the crystallization of PLLA and act as the new shape fixed phase to prevent the irreversible sliding of polymer chains during deformation, accounting for the enhanced shape recovery ratio; on the other hand, storage modulus of the composite at high temperature has been improved with the aid of GO and its excellent dispersion in the PLLA matrix, resulting in higher recovery stress. Our result opens a new avenue for mass production of thermoplastic shape memory PLLA-based composites with enhanced mechanical and shape recovery properties. |
| 语种 | 英语 |
| 源URL | [http://ir.sinap.ac.cn/handle/331007/31874]  |
| 专题 | 上海应用物理研究所_中科院上海应用物理研究所2011-2017年 |
| 作者单位 | 1.Chinese Acad Sci, Shanghai Inst Appl Phys, Shanghai 201800, Peoples R China; 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China; 3.Hangzhou Normal Univ, Coll Mat Chem & Chem Engn, Hangzhou 310036, Zhejiang, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhao, JX,Li, JY,Li, YJ,et al. Thermoplastic shape memory composites with enhanced recovery stress and recovery ratio based on double roles of PVAc-g-GO[J]. COMPOSITES COMMUNICATIONS,2019,13(-):52—56. |
| APA | Zhao, JX,Li, JY,Li, YJ,&You, JC.(2019).Thermoplastic shape memory composites with enhanced recovery stress and recovery ratio based on double roles of PVAc-g-GO.COMPOSITES COMMUNICATIONS,13(-),52—56. |
| MLA | Zhao, JX,et al."Thermoplastic shape memory composites with enhanced recovery stress and recovery ratio based on double roles of PVAc-g-GO".COMPOSITES COMMUNICATIONS 13.-(2019):52—56. |
入库方式： OAI收割
来源：上海应用物理研究所
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