Preparation of dense Ta-LLZO/MgO composite Li-ion solid electrolyte: Sintering, microstructure, performance and the role of MgO
文献类型：期刊论文
| 作者 | Huang, Xiao; Lu, Yang; Song, Zhen; Xiu, Tongping; Badding, Michael E.; Wen, Zhaoyin |
| 刊名 | JOURNAL OF ENERGY CHEMISTRY
 |
| 出版日期 | 2019-12-01 |
| 卷号 | 39页码:8 |
| ISSN号 | 2095-4956 |
| 关键词 | Li-Garnet Solid electrolyte Mechanism Critical current density Sintering |
| DOI | 10.1016/j.jechem.2019.01.013 |
| 文献子类 | Article |
| 英文摘要 | Cubic phase Li7La3Zr2O12 (LLZO), a member of the Li-Garnet family, is a promising solid electrolyte and has been widely studied in recent years. However, LLZO samples prepared via conventional ambient air sintering reported in the published literature often contain large grains with lower than desired (<94%) relative density. In this study, a non-contact method of co-firing with mother powder method is proposed to prepare high-quality Ta-doped LLZO-MgO composite ceramics. By sintering at 1150 degrees C for 5 h, the ceramics can reach relative density of 98.2%, conductivity of 5.17 x 10(-4) S cm(-1) at 25 degrees C and fracture strength of similar to 150 MPa. The sintered samples have uniform fine-grained microstructure and high critical current densities of 0.75-0.95 mA cm(-2) at room temperature in Li-Li symmetry cell with Au modification. In addition, systematic sintering experiments and characterizations are conducted to explore the function of MgO in inhibiting the Ta-LLZO grain growth and its existing form inside the composite ceramics. (C) 2019 Science Press and Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier B.V. and Science Press. All rights reserved. |
| WOS研究方向 | Chemistry ; Energy & Fuels ; Engineering |
| 语种 | 英语 |
| 出版者 | ELSEVIER |
| 源URL | [http://ir.sic.ac.cn/handle/331005/26701]  |
| 专题 | 中国科学院上海硅酸盐研究所 |
| 推荐引用方式 GB/T 7714 | Huang, Xiao,Lu, Yang,Song, Zhen,et al. Preparation of dense Ta-LLZO/MgO composite Li-ion solid electrolyte: Sintering, microstructure, performance and the role of MgO[J]. JOURNAL OF ENERGY CHEMISTRY,2019,39:8. |
| APA | Huang, Xiao,Lu, Yang,Song, Zhen,Xiu, Tongping,Badding, Michael E.,&Wen, Zhaoyin.(2019).Preparation of dense Ta-LLZO/MgO composite Li-ion solid electrolyte: Sintering, microstructure, performance and the role of MgO.JOURNAL OF ENERGY CHEMISTRY,39,8. |
| MLA | Huang, Xiao,et al."Preparation of dense Ta-LLZO/MgO composite Li-ion solid electrolyte: Sintering, microstructure, performance and the role of MgO".JOURNAL OF ENERGY CHEMISTRY 39(2019):8. |
入库方式： OAI收割
来源：上海硅酸盐研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。