TiN-Ni Cermets with High Oxidation Resistance and Electrical Conductivity as Candidates for Intermediate-Temperature Solid Oxide Fuel Cell Interconnects
文献类型:期刊论文
作者 | Duan, Hang; Liu, Yan; Qi, Qian; Zhang, Hui; Huang, Zhengren |
刊名 | JOM |
出版日期 | 2019-11-01 |
卷号 | 71期号:11页码:3782 |
ISSN号 | 1047-4838 |
DOI | 10.1007/s11837-019-03418-7 |
文献子类 | Article |
英文摘要 | Novel TiN-Ni cermets with high oxidation resistance and excellent electrical conductivity were developed and evaluated as intermediate-temperature solid oxide fuel cells (IT-SOFCs) interconnects. Three TiN-Ni cermets with 30 vol.%, 50 vol.% and 70 vol.% Ni were prepared by optimizing hot-pressed sintering parameters. Their oxidation kinetics was systematically investigated in air at 600-800 degrees C. Relative density, oxidation rate constant and electrical conductivity can be readily optimized by adjusting the Ni content in the cermets, and their corresponding maximum values reached 99.6%, 2.56 x 10(-11) g(2) cm(-4) s(-1) (at 800 degrees C) and 1.5 x 10(4) S cm(-1) (500 h oxidation reaction at 800 degrees C). Coefficient of thermal expansion could be adjusted as well in the 9.7 x 10(-6) k(-1) to 13.2 x 10(-6) k(-1) range to match with the IT-SOFCs components. The electrical conductivity of all samples studied in this work was above 1.0 x 10(4) S cm(-1), which is much higher than that of all other cermets reported in the literature. We demonstrated that TiN-Ni cermets are promising material as candidates for IT-SOFCs interconnects. |
WOS研究方向 | Materials Science ; Metallurgy & Metallurgical Engineering ; Mineralogy ; Mining & Mineral Processing |
语种 | 英语 |
出版者 | SPRINGER |
源URL | [http://ir.sic.ac.cn/handle/331005/26737] |
专题 | 中国科学院上海硅酸盐研究所 |
推荐引用方式 GB/T 7714 | Duan, Hang,Liu, Yan,Qi, Qian,et al. TiN-Ni Cermets with High Oxidation Resistance and Electrical Conductivity as Candidates for Intermediate-Temperature Solid Oxide Fuel Cell Interconnects[J]. JOM,2019,71(11):3782. |
APA | Duan, Hang,Liu, Yan,Qi, Qian,Zhang, Hui,&Huang, Zhengren.(2019).TiN-Ni Cermets with High Oxidation Resistance and Electrical Conductivity as Candidates for Intermediate-Temperature Solid Oxide Fuel Cell Interconnects.JOM,71(11),3782. |
MLA | Duan, Hang,et al."TiN-Ni Cermets with High Oxidation Resistance and Electrical Conductivity as Candidates for Intermediate-Temperature Solid Oxide Fuel Cell Interconnects".JOM 71.11(2019):3782. |
入库方式: OAI收割
来源:上海硅酸盐研究所
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