Facile synthesis approach for preparation of robust and recyclable Ag/ZnO nanorods with high catalytic activity for 4-nitrophenol reduction
文献类型：期刊论文
| 作者 | Rasaki, Sefiu Abolaji; Zhao, Chunlei; Wang, Rui; Wang, Jiacheng; Jiang, Heng; Yang, Minghui |
| 刊名 | MATERIALS RESEARCH BULLETIN
 |
| 出版日期 | 2019-11-01 |
| 卷号 | 119 |
| 关键词 | Ag/ZnO nanorods catalyst 4-nitrophenol reduction Pseudo-first-order kinetics Chemisorptive reactionrecyclability |
| ISSN号 | 0025-5408 |
| DOI | 10.1016/j.materresbull.2019.110536 |
| 文献子类 | Article |
| 英文摘要 | In this work, Ag/ZnO nanorods are prepared via simple and cost-saving liquid precipitation citrate reduction process (LPCR). The system shows appreciable catalytic activity for the reduction of 4-nitrophenol (4-NP) to 4-aminophenol (4-AP) wherein NaBH4 is used as electron sacrificer at ambience. It is found out that ZnO nanorods can effectively prevent Ag NPs agglomeration; a problem normally reduces active sites density. The coupling effect between the Ag NPs and ZnO greatly enhances electron transfer rate. This gives rise to high reduction rate constant (k(app)) of (similar to)3.97 x 10(-3) s(-1) for the catalytic reduction of 4-NP. The result is about 1.9times better than that of Ag NPs (2.07 x 10(-3) s(-1)). The k(app), is well fitted into pseudo-first order kinetics with high correlation coefficient (R-2) of about 0.994, indicating chemisorptive reduction process. The remarkable performance obtained here is attributed to strong coupling effect between Ag NPs and ZnO nanorods derived from LPCR synthesis method. |
| WOS研究方向 | Materials Science |
| 语种 | 英语 |
| 出版者 | PERGAMON-ELSEVIER SCIENCE LTD |
| 源URL | [http://ir.sic.ac.cn/handle/331005/26749]  |
| 专题 | 中国科学院上海硅酸盐研究所 |
| 推荐引用方式 GB/T 7714 | Rasaki, Sefiu Abolaji,Zhao, Chunlei,Wang, Rui,et al. Facile synthesis approach for preparation of robust and recyclable Ag/ZnO nanorods with high catalytic activity for 4-nitrophenol reduction[J]. MATERIALS RESEARCH BULLETIN,2019,119. |
| APA | Rasaki, Sefiu Abolaji,Zhao, Chunlei,Wang, Rui,Wang, Jiacheng,Jiang, Heng,&Yang, Minghui.(2019).Facile synthesis approach for preparation of robust and recyclable Ag/ZnO nanorods with high catalytic activity for 4-nitrophenol reduction.MATERIALS RESEARCH BULLETIN,119. |
| MLA | Rasaki, Sefiu Abolaji,et al."Facile synthesis approach for preparation of robust and recyclable Ag/ZnO nanorods with high catalytic activity for 4-nitrophenol reduction".MATERIALS RESEARCH BULLETIN 119(2019). |
入库方式： OAI收割
来源：上海硅酸盐研究所
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