Perovskite films with a sacrificial cation for solar cells with enhanced stability based on carbon electrodes
文献类型：期刊论文
| 作者 | Li, Haiyan; Yang, Songwang; Gong, Shuiping; Wu, Jiawei; Pan, Shangke; Chen, Zongqi; Zhao, Qingbao; Shou, Chunhui; Shen, Qu |
| 刊名 | JOURNAL OF ALLOYS AND COMPOUNDS
 |
| 出版日期 | 2019-08-15 |
| 卷号 | 797页码:811 |
| ISSN号 | 0925-8388 |
| 关键词 | Sacrificial cation Tetrabutylammonium iodide (TBA) Carbon electrode Perovskite solar cells Stability |
| DOI | 10.1016/j.jallcom.2019.05.148 |
| 文献子类 | Article |
| 英文摘要 | Organic-inorganic lead halide perovskite solar cells have high power conversion efficiency; however, their poor environmental stability is still a problem that needs to be solved. In this study, a tetrabutylammonium cation is introduced into mixed-cation lead a mixed-halide Cs-0.05(FA(0.83-)MA(0.17))(0.95)Pb(I0.83Br0.17)(3) perovskite as a sacrificial cation to enhance the stability of the corresponding solar cells. Tetrabutylammonium cations located at grain boundaries are beneficial for the formation of two-dimensional perovskite grains perpendicular to the substrate during heat treatment, which can enhance the stability of solar cells against moisture. By optimizing the content of tetrabutylammonium iodide ions, a maximum power conversion efficiency of 12% is achieved for the solar cell with the structure of FTO/c-TiO2/m-TiO2/perovskite/carbon. Without encapsulation, the tetrabutylammonium contained perovskite solar cell does not obviously degrade at ambient atmosphere (60% relative humidity and 27 degrees C) for over 1000 h. Moreover, this solar cell can retain over 80% of its initial efficiency for 500 h at 85 degrees C and in dry air. (C) 2019 Elsevier B.V. All rights reserved. |
| WOS研究方向 | Chemistry ; Materials Science ; Metallurgy & Metallurgical Engineering |
| 语种 | 英语 |
| 出版者 | ELSEVIER SCIENCE SA |
| 源URL | [http://ir.sic.ac.cn/handle/331005/26908]  |
| 专题 | 中国科学院上海硅酸盐研究所 |
| 推荐引用方式 GB/T 7714 | Li, Haiyan,Yang, Songwang,Gong, Shuiping,et al. Perovskite films with a sacrificial cation for solar cells with enhanced stability based on carbon electrodes[J]. JOURNAL OF ALLOYS AND COMPOUNDS,2019,797:811. |
| APA | Li, Haiyan.,Yang, Songwang.,Gong, Shuiping.,Wu, Jiawei.,Pan, Shangke.,...&Shen, Qu.(2019).Perovskite films with a sacrificial cation for solar cells with enhanced stability based on carbon electrodes.JOURNAL OF ALLOYS AND COMPOUNDS,797,811. |
| MLA | Li, Haiyan,et al."Perovskite films with a sacrificial cation for solar cells with enhanced stability based on carbon electrodes".JOURNAL OF ALLOYS AND COMPOUNDS 797(2019):811. |
入库方式： OAI收割
来源：上海硅酸盐研究所
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