Cryogenic Exfoliation of Non-layered Magnesium into Two-Dimensional Crystals
文献类型：期刊论文
| 作者 | Zhang, Chen; Xu, Yingfeng; Lu, Ping; Wei, Chenyang; Zhu, Chenxi; Yao, Heliang; Xu, Fangfang; Shi, Jianlin |
| 刊名 | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
 |
| 出版日期 | 2019-06-24 |
| 卷号 | 58期号:26页码:8814 |
| 关键词 | cryogenic cleavage metallic crystals physical exfoliation two-dimensional Mg |
| ISSN号 | 1433-7851 |
| DOI | 10.1002/anie.201903485 |
| 文献子类 | Article |
| 英文摘要 | Physical exfoliation of layered precursors is one of the most prevailing techniques to prepare two-dimensional (2D) crystals, which, however, is considered to be intrinsically inapplicable to non-layered bulks. Now, plane cleavage differentiation is identified in metallic magnesium at cryogenic temperature (CT), and a cryogenic exfoliation strategy of non-layered magnesium into 2D crystals is developed. The cleavage anisotropy of the Mg lattice in response to the external mechanical stress originates from the CT-induced specific inactivation of basal slip, which results in the basal cleavage perpendicular to c axis. The exfoliated novel 2D Mg crystals exhibit remarkable localized surface plasmon resonances, holding great promise for the applications in harvesting and converting solar energy. Beyond creating a new member for the burgeoning 2D family, this study may provide a useful tool for the physical exfoliations of various non-layered materials. |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| 源URL | [http://ir.sic.ac.cn/handle/331005/27039]  |
| 专题 | 中国科学院上海硅酸盐研究所 |
| 推荐引用方式 GB/T 7714 | Zhang, Chen,Xu, Yingfeng,Lu, Ping,et al. Cryogenic Exfoliation of Non-layered Magnesium into Two-Dimensional Crystals[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,2019,58(26):8814. |
| APA | Zhang, Chen.,Xu, Yingfeng.,Lu, Ping.,Wei, Chenyang.,Zhu, Chenxi.,...&Shi, Jianlin.(2019).Cryogenic Exfoliation of Non-layered Magnesium into Two-Dimensional Crystals.ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,58(26),8814. |
| MLA | Zhang, Chen,et al."Cryogenic Exfoliation of Non-layered Magnesium into Two-Dimensional Crystals".ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 58.26(2019):8814. |
入库方式： OAI收割
来源：上海硅酸盐研究所
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