Two Deep Ultraviolet Hydrated Borate Crystals: Centrosymmetric LiRbB5O8(OH)center dot H2O and Non-Centrosymmetric K2B5O8(OH)center dot 2H(2)O
文献类型：期刊论文
| 作者 | Shi, Yutong; Luo, Min; Lin, Chensheng; Peng, Guang; Ye, Ning |
| 刊名 | CRYSTAL GROWTH & DESIGN
 |
| 出版日期 | 2019-05-01 |
| 卷号 | 19期号:5页码:3052 |
| ISSN号 | 1528-7483 |
| DOI | 10.1021/acs.cgd.9b00365 |
| 文献子类 | Article |
| 英文摘要 | Two hydrated borate crystals, namely, centrosymmetric LiRbB5O8(OH)center dot H2O (LRB) and non-centrosymmetric K2B5O8(OH)center dot 2H(2)O (K2B5), were successfully synthesized by a solvothermal technique. Although two titled compounds have the same fundamental building block B5O10(OH), the distinct linkage modes make them exhibit completely different structures. Compounds LRB and K2B5 crystallize in the nonpolar space group of P2(1)/n and polar space group Pna2(1), respectively. Thermal analyses of both compounds were performed. Besides, they had short UV cutoff edge (<200 nm) according to UV-vis-NIR diffuse reflectance spectroscopy. Significantly, compound K2B5 exhibited a high laser damage threshold and moderate second harmonic generation intensity (0.84 x KDP). Furthermore, the optical properties and electronic structures of both compounds have been well studied by the density functional theory method. |
| WOS研究方向 | Chemistry ; Crystallography ; Materials Science |
| 语种 | 英语 |
| 出版者 | AMER CHEMICAL SOC |
| 源URL | [http://ir.sic.ac.cn/handle/331005/27144]  |
| 专题 | 中国科学院上海硅酸盐研究所 |
| 推荐引用方式 GB/T 7714 | Shi, Yutong,Luo, Min,Lin, Chensheng,et al. Two Deep Ultraviolet Hydrated Borate Crystals: Centrosymmetric LiRbB5O8(OH)center dot H2O and Non-Centrosymmetric K2B5O8(OH)center dot 2H(2)O[J]. CRYSTAL GROWTH & DESIGN,2019,19(5):3052. |
| APA | Shi, Yutong,Luo, Min,Lin, Chensheng,Peng, Guang,&Ye, Ning.(2019).Two Deep Ultraviolet Hydrated Borate Crystals: Centrosymmetric LiRbB5O8(OH)center dot H2O and Non-Centrosymmetric K2B5O8(OH)center dot 2H(2)O.CRYSTAL GROWTH & DESIGN,19(5),3052. |
| MLA | Shi, Yutong,et al."Two Deep Ultraviolet Hydrated Borate Crystals: Centrosymmetric LiRbB5O8(OH)center dot H2O and Non-Centrosymmetric K2B5O8(OH)center dot 2H(2)O".CRYSTAL GROWTH & DESIGN 19.5(2019):3052. |
入库方式： OAI收割
来源：上海硅酸盐研究所
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