Effect of Mn-doping on dielectric and energy storage properties of (Pb0.91La0.06)(Zr0.96Ti0.04)O-3 antiferroelectric ceramics
文献类型：期刊论文
| 作者 | Qiao, Peixin; Zhang, Youfeng; Chen, Xuefeng; Zhou, Mingxing; Wang, Genshui; Dong, Xianlin |
| 刊名 | JOURNAL OF ALLOYS AND COMPOUNDS
 |
| 出版日期 | 2019-04-05 |
| 卷号 | 780页码:581 |
| ISSN号 | 0925-8388 |
| 关键词 | Antiferroelectric ceramics Mn-doping Energy storage performance |
| DOI | 10.1016/j.jallcom.2018.11.371 |
| 文献子类 | Article |
| 英文摘要 | Bulk ceramics with high recoverable energy density (W-re) and energy efficiency (eta) play a critical role in the development of pulsed power systems for miniaturization and lightweight. The orthorhombic phase (Pb,La)(Zr,Ti)O-3-based antiferroelectric (AFE) ceramics have been regarded as one of the most promising candidates for pulsed power system applications due to their relatively high energy storage density and efficiency. However, the main drawback of orthorhombic phase (Pb,La)(Zr,Ti)O-3-based AFE ceramics is relatively low dielectric breakdown strengthen (DBS), which has always restricted the improvement of energy storage density. In this study, an effectively method to increase DBS by the introduction of Mn has been proposed. The relative density of orthorhombic phase (Pb0.91La0.06)(Zr0.96Ti0.04)O-3 (PLZT) ceramics was improved by Mn-doping. And the introduction of Mn can decrease the tolerance factor (t) of PLZT ceramics because the radius of Mn2+ is larger than that of B-site Zr4+/Ti4+, and thus enhancing antiferroelectricity. Meanwhile, the effects of Mn-doping on the phase structure, microstructure and dielectric properties of PLZT ceramics have been studied thoroughly in this study. It is found that the highest W-re of 7.65 J/cm(3) is obtained at 1.0 mol% Mn-doped PLZT ceramic, which is obviously larger than that of undoped PLZT ceramic (5.71 J/cm(3)). These results suggest that the Mn-doped PLZT ceramics are potential energy storage materials in pulsed power systems. (C) 2018 Published by Elsevier B.V. |
| WOS研究方向 | Chemistry ; Materials Science ; Metallurgy & Metallurgical Engineering |
| 语种 | 英语 |
| 出版者 | ELSEVIER SCIENCE SA |
| 源URL | [http://ir.sic.ac.cn/handle/331005/27200]  |
| 专题 | 中国科学院上海硅酸盐研究所 |
| 推荐引用方式 GB/T 7714 | Qiao, Peixin,Zhang, Youfeng,Chen, Xuefeng,et al. Effect of Mn-doping on dielectric and energy storage properties of (Pb0.91La0.06)(Zr0.96Ti0.04)O-3 antiferroelectric ceramics[J]. JOURNAL OF ALLOYS AND COMPOUNDS,2019,780:581. |
| APA | Qiao, Peixin,Zhang, Youfeng,Chen, Xuefeng,Zhou, Mingxing,Wang, Genshui,&Dong, Xianlin.(2019).Effect of Mn-doping on dielectric and energy storage properties of (Pb0.91La0.06)(Zr0.96Ti0.04)O-3 antiferroelectric ceramics.JOURNAL OF ALLOYS AND COMPOUNDS,780,581. |
| MLA | Qiao, Peixin,et al."Effect of Mn-doping on dielectric and energy storage properties of (Pb0.91La0.06)(Zr0.96Ti0.04)O-3 antiferroelectric ceramics".JOURNAL OF ALLOYS AND COMPOUNDS 780(2019):581. |
入库方式： OAI收割
来源：上海硅酸盐研究所
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