Chiral Recognition of Hexahelicene on a Surface via the Forming of Asymmetric Heterochiral Trimers
文献类型：期刊论文
| 作者 | Zhang, Hong; Liu, Hong; Shen, Chengshuo; Gan, Fuwei; Su, Xuelei; Qiu, Huibin; Yang, Bo; Yu, Ping |
| 刊名 | INTERNATIONAL JOURNAL OF MOLECULAR SCIENCES
 |
| 出版日期 | 2019-04-02 |
| 卷号 | 20期号:8 |
| 关键词 | chiral recognition helicene assembly STM nc-AFM |
| ISSN号 | 1422-0067 |
| DOI | 10.3390/ijms20082018 |
| 文献子类 | Article |
| 英文摘要 | Chiral recognition among helical molecules is of essential importance in many chemical and biochemical processes. The complexity necessitates investigating manageable model systems for unveiling the fundamental principles of chiral recognition at the molecular level. Here, we reported chiral recognition in the self-assembly of enantiopure and racemic hexahelicene on a Au(111) surface. Combing scanning tunneling microscopy (STM) and atomic force microscopy (AFM) measurements, the asymmetric heterochiral trimers were observed as a new type of building block in racemic helicene self-assembly on Au(111). The intermolecular recognition of the heterochiral trimer was investigated upon manual separation so that the absolute configuration of each helicene molecule was unambiguously determined one by one, thus confirming that the trimer was 2+1 in handedness. These heterochiral trimers showed strong stability upon different coverages, which was also supported by theoretical calculations. Our results provide valuable insights for understanding the intermolecular recognition of helical molecules. |
| WOS研究方向 | Biochemistry & Molecular Biology ; Chemistry |
| 语种 | 英语 |
| 出版者 | MDPI |
| 源URL | [http://ir.sic.ac.cn/handle/331005/27206]  |
| 专题 | 中国科学院上海硅酸盐研究所 |
| 推荐引用方式 GB/T 7714 | Zhang, Hong,Liu, Hong,Shen, Chengshuo,et al. Chiral Recognition of Hexahelicene on a Surface via the Forming of Asymmetric Heterochiral Trimers[J]. INTERNATIONAL JOURNAL OF MOLECULAR SCIENCES,2019,20(8). |
| APA | Zhang, Hong.,Liu, Hong.,Shen, Chengshuo.,Gan, Fuwei.,Su, Xuelei.,...&Yu, Ping.(2019).Chiral Recognition of Hexahelicene on a Surface via the Forming of Asymmetric Heterochiral Trimers.INTERNATIONAL JOURNAL OF MOLECULAR SCIENCES,20(8). |
| MLA | Zhang, Hong,et al."Chiral Recognition of Hexahelicene on a Surface via the Forming of Asymmetric Heterochiral Trimers".INTERNATIONAL JOURNAL OF MOLECULAR SCIENCES 20.8(2019). |
入库方式： OAI收割
来源：上海硅酸盐研究所
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