Composite Solid Polymer Electrolyte with Garnet Nanosheets in Poly(ethylene oxide)
文献类型：期刊论文
| 作者 | Song, Shufeng; Wu, Yongmin; Tang, Weiping; Deng, Fan; Yao, Jianyao; Liu, Zongwen; Hu, Rongjie; Alamusi; Wen, Zhaoyin; Lu, Li |
| 刊名 | ACS SUSTAINABLE CHEMISTRY & ENGINEERING
 |
| 出版日期 | 2019-04-01 |
| 卷号 | 7期号:7页码:7163 |
| 关键词 | Garnet nanosheet PEO Composite polymer electrolyte Conductivity |
| ISSN号 | 2168-0485 |
| DOI | 10.1021/acssuschemeng.9b00143 |
| 文献子类 | Article |
| 英文摘要 | Solid electrolytes potentially provide safety, Li dendrites blocking, and electrochemical stability in Li-metal batteries. Large efforts have been devoted to disperse ceramic in a poly(ethylene oxide) (PEO) matrix to improve the ions transport. However, it is challengeable to create efficient framework for ions transport with nano-particles. Here we report for the first time garnet nanosheets to provide interconnected Li-ions transport pathway in a PEO matrix. The garnet nanosheet fillers would not only facilitate ions transport but also enhance ionic conductivity in comparison with their nanoparticle counterparts. A composite solid polymer electrolyte containing 15 wt % garnet nanosheets exhibits a practically useful conductivity of 3.6 x 10(-4) S cm(-1) at room temperature. Besides, the composite electrolyte can robustly isolate Li dendrites in a symmetric lithium metal-composite electrolyte battery during reversible Li dissolution/deposition at a relatively low temperature of 40 degrees C. The symmetric cell with composite electrolyte shows flat voltage and low interfacial resistance over a galvanostatic cycling of 200 h at a current density of 0.1 mA cm(-2). A solid-state Li/LiFePO4 battery with the composite polymer electrolyte exhibits a capacity of 98.1 mAh g(-1) and a capacity retention of 97.5% after 30 cycles at a temperature of 40 degrees C. This finding provides a strategy to explore superionic conductors. |
| WOS研究方向 | Chemistry ; Science & Technology - Other Topics ; Engineering |
| 语种 | 英语 |
| 出版者 | AMER CHEMICAL SOC |
| 源URL | [http://ir.sic.ac.cn/handle/331005/27221]  |
| 专题 | 中国科学院上海硅酸盐研究所 |
| 推荐引用方式 GB/T 7714 | Song, Shufeng,Wu, Yongmin,Tang, Weiping,et al. Composite Solid Polymer Electrolyte with Garnet Nanosheets in Poly(ethylene oxide)[J]. ACS SUSTAINABLE CHEMISTRY & ENGINEERING,2019,7(7):7163. |
| APA | Song, Shufeng.,Wu, Yongmin.,Tang, Weiping.,Deng, Fan.,Yao, Jianyao.,...&Hu, Ning.(2019).Composite Solid Polymer Electrolyte with Garnet Nanosheets in Poly(ethylene oxide).ACS SUSTAINABLE CHEMISTRY & ENGINEERING,7(7),7163. |
| MLA | Song, Shufeng,et al."Composite Solid Polymer Electrolyte with Garnet Nanosheets in Poly(ethylene oxide)".ACS SUSTAINABLE CHEMISTRY & ENGINEERING 7.7(2019):7163. |
入库方式： OAI收割
来源：上海硅酸盐研究所
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