Facile synthesis of hydrated magnesium vanadium bronze sigma-Mg0.25V2O5 center dot H2O as a novel cathode material for lithium-ion batteries
文献类型：期刊论文
| 作者 | Ma, Yining; Zhou, Huaijuan; Li, Rong; Huang, Aibin; Cao, Xun; Yao, Heliang; Bao, Shanhu; Ji, Shidong; Jin, Ping |
| 刊名 | JOURNAL OF ALLOYS AND COMPOUNDS
 |
| 出版日期 | 2019-03-10 |
| 卷号 | 777页码:931 |
| 关键词 | sigma-Mg0.25V2O5 center dot H2O Long-term cyclic stability Cathode material Lithium-ion batteries Vanadium bronze |
| ISSN号 | 0925-8388 |
| DOI | 10.1016/j.jallcom.2018.11.054 |
| 文献子类 | Article |
| 英文摘要 | Square block-like sigma-Mg0.25V2O5 center dot H2O with an open layered framework has been successfully synthesized via a facile hydrothermal method. The entire synthetic process is efficient and economically beneficial. As a cathode material for lithium-ion batteries, the hydrated magnesium vanadium bronze exhibits a high reversible capacity and excellent cycling stability at high current rates. High discharge capacities of 294.2 and 221 mA h g(-1) can be obtained at the current densities of 20 and 100 mA g(-1), respectively. Meanwhile, the electrode achieves a capacity retention of 87.12% after 100 cycles at 100 mA g(-1) and has an excellent long-term cyclic stability with an average decay of 0.053% per cycle over 400 cycles at 800 mA g(-1). The structural stability and impedance variation of the sigma-Mg0.25V2O5 center dot H2O electrodes upon cycling have also been investigated. The excellent electrochemical performance suggests that the layered Mg0.25V2O5 center dot H2O could be a promising candidate for the cathode material of lithium-ion batteries. (C) 2018 Elsevier B.V. All rights reserved. |
| WOS研究方向 | Chemistry ; Materials Science ; Metallurgy & Metallurgical Engineering |
| 语种 | 英语 |
| 出版者 | ELSEVIER SCIENCE SA |
| 源URL | [http://ir.sic.ac.cn/handle/331005/27283]  |
| 专题 | 中国科学院上海硅酸盐研究所 |
| 推荐引用方式 GB/T 7714 | Ma, Yining,Zhou, Huaijuan,Li, Rong,et al. Facile synthesis of hydrated magnesium vanadium bronze sigma-Mg0.25V2O5 center dot H2O as a novel cathode material for lithium-ion batteries[J]. JOURNAL OF ALLOYS AND COMPOUNDS,2019,777:931. |
| APA | Ma, Yining.,Zhou, Huaijuan.,Li, Rong.,Huang, Aibin.,Cao, Xun.,...&Jin, Ping.(2019).Facile synthesis of hydrated magnesium vanadium bronze sigma-Mg0.25V2O5 center dot H2O as a novel cathode material for lithium-ion batteries.JOURNAL OF ALLOYS AND COMPOUNDS,777,931. |
| MLA | Ma, Yining,et al."Facile synthesis of hydrated magnesium vanadium bronze sigma-Mg0.25V2O5 center dot H2O as a novel cathode material for lithium-ion batteries".JOURNAL OF ALLOYS AND COMPOUNDS 777(2019):931. |
入库方式： OAI收割
来源：上海硅酸盐研究所
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