Textured Sr2Sc0.1Nb0.1Co1.5Fe0.3O6-2 Thin Film Cathodes for IT-SOFCs
文献类型:期刊论文
作者 | Zhu, Zhaoxin; Zhou, Chuan; Zhou, Wei; Yang, Nan |
刊名 | MATERIALS
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出版日期 | 2019-03-01 |
卷号 | 12期号:5 |
关键词 | SOFCs mixed ionic electronic conductor ORR thin films surface chemistry |
ISSN号 | 1996-1944 |
DOI | 10.3390/ma12050777 |
文献子类 | Article |
英文摘要 | Reducing the operating temperature of solid oxide fuel cells (SOFCs) to intermediate (650-850 degrees C) or even lower levels (400-650 degrees C) is an important practical requirement. However, the main obstacle to lowering the operating temperature is the poor oxygen reduction reaction (ORR) activity on the cathode side and, therefore, it is essential to explore cathode materials with good ORR activity in these temperature ranges. In this work, we investigated the possibility of using Sr2Sc0.1Nb0.1Co1.5Fe0.3O6-2 (SSNCF) as a suitable intermediate temperature cathode material. SSNCF thin films with different orientations were prepared using the pulsed laser deposition technique, and the relationship of the surface chemical states and ORR activity was discussed in terms of crystallographic orientation. The results showed that the SSNCF/YSZ grown along the [110] direction exhibited superior ORR activity compared to the SSNCF/SDC/YSZ thin film electrode grown along the [100] direction. This was explained by the variation in the Sr-surface enrichment and cobalt ion oxidation state using X-ray photoemission spectroscopy. |
WOS研究方向 | Materials Science |
语种 | 英语 |
出版者 | MDPI |
源URL | [http://ir.sic.ac.cn/handle/331005/27293] ![]() |
专题 | 中国科学院上海硅酸盐研究所 |
推荐引用方式 GB/T 7714 | Zhu, Zhaoxin,Zhou, Chuan,Zhou, Wei,et al. Textured Sr2Sc0.1Nb0.1Co1.5Fe0.3O6-2 Thin Film Cathodes for IT-SOFCs[J]. MATERIALS,2019,12(5). |
APA | Zhu, Zhaoxin,Zhou, Chuan,Zhou, Wei,&Yang, Nan.(2019).Textured Sr2Sc0.1Nb0.1Co1.5Fe0.3O6-2 Thin Film Cathodes for IT-SOFCs.MATERIALS,12(5). |
MLA | Zhu, Zhaoxin,et al."Textured Sr2Sc0.1Nb0.1Co1.5Fe0.3O6-2 Thin Film Cathodes for IT-SOFCs".MATERIALS 12.5(2019). |
入库方式: OAI收割
来源:上海硅酸盐研究所
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