Noble metal (Pt, Au@Pd) nanoparticles supported on metal organic framework (MOF-74) nanoshuttles as high-selectivity CO2 conversion catalysts
文献类型：期刊论文
| 作者 | Han, Yuqing; Xu, Haitao; Su, Yuqun; Xu, Zhen-liang; Wang, Kefu; Wang, Wenzhong |
| 刊名 | JOURNAL OF CATALYSIS
 |
| 出版日期 | 2019-02-01 |
| 卷号 | 370页码:70 |
| 关键词 | Metal-organic framework Nanoshuttle MOF-74 Noble metal catalyst Reverse water-gas shift reaction CO2 photoreduction reaction |
| ISSN号 | 0021-9517 |
| DOI | 10.1016/j.jcat.2018.12.005 |
| 文献子类 | Article |
| 英文摘要 | The Zn-based metal-organic framework (MOF) catalysts MOF-74, Au@Pd@MOF-74, Pt/MOF-74, and Pt/Au@Pd@MOF-74, were assembled. Core-shell Au@Pd, in which Au nanoparticles (NPs) serve as the core for the epitaxial growth of Pd shells, was encapsulated into MOF-74 nanoshuttles to control the MOF-74 morphology and impart NP functionality. Pt NPs were loaded onto the MOF-74 surface. Pt/MOF-74 catalyzed CO2 conversion at 99.7% CO selectivity in the reverse water-gas shift (RWGS) reaction, and Au@Pd@MOF-74 photocatalyzed CO2 with 100% CO selectivity. Importantly, the catalyst Pt/Au@Pd@MOF-74, not only catalyzed the conversion of CO2 to CO in RWGS with 99.6% selectivity, but also photocatalyzed CO2 to CH4 at low concentration (800 PPm) (C) 2018 Elsevier Inc. All rights reserved. |
| WOS研究方向 | Chemistry ; Engineering |
| 语种 | 英语 |
| 出版者 | ACADEMIC PRESS INC ELSEVIER SCIENCE |
| 源URL | [http://ir.sic.ac.cn/handle/331005/27358]  |
| 专题 | 中国科学院上海硅酸盐研究所 |
| 推荐引用方式 GB/T 7714 | Han, Yuqing,Xu, Haitao,Su, Yuqun,et al. Noble metal (Pt, Au@Pd) nanoparticles supported on metal organic framework (MOF-74) nanoshuttles as high-selectivity CO2 conversion catalysts[J]. JOURNAL OF CATALYSIS,2019,370:70. |
| APA | Han, Yuqing,Xu, Haitao,Su, Yuqun,Xu, Zhen-liang,Wang, Kefu,&Wang, Wenzhong.(2019).Noble metal (Pt, Au@Pd) nanoparticles supported on metal organic framework (MOF-74) nanoshuttles as high-selectivity CO2 conversion catalysts.JOURNAL OF CATALYSIS,370,70. |
| MLA | Han, Yuqing,et al."Noble metal (Pt, Au@Pd) nanoparticles supported on metal organic framework (MOF-74) nanoshuttles as high-selectivity CO2 conversion catalysts".JOURNAL OF CATALYSIS 370(2019):70. |
入库方式： OAI收割
来源：上海硅酸盐研究所
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