Synthesis of AuPd nanoparticle-decorated graphene-coated ZnO nanorod arrays with enhanced photoelectrochemical performance and stability
文献类型:期刊论文
作者 | Zhang, Yuzhi; Zhang, Yunlong; Guo, Yunfeng; Wu, Lingnan; Liu, Yangqiao; Song, Lixing |
刊名 | RSC ADVANCES
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出版日期 | 2019-01-23 |
卷号 | 9期号:5页码:2666 |
ISSN号 | 2046-2069 |
DOI | 10.1039/c8ra09028a |
文献子类 | Article |
英文摘要 | AuPd nanoparticle-decorated graphene-coated ZnO nanorod (ZNR) array electrodes (ZNR@Gr/AuPd) were synthesized via electrostatic self-assembly followed by solution reduction methods. The morphologies of ZNR@Gr/AuPd were characterized with scanning electron microscopy (SEM), transmission electron microscopy (TEM), and atomic force microscopy (AFM), which indicated that ZNR was well-coated by graphene with 3-5 layers and uniformly decorated with AuPd nanoparticles (about 5 nm). UV-Vis diffuse reflectance and photoluminescence spectra were obtained to analyze the optical properties. The photoelectrochemical (PEC) properties were also evaluated; the results indicated that the photocurrent density was 2.27 mA cm(-2) at 0.8 V versus Ag/AgCl, which was 7.1 times that of bare ZNR. The sample also displayed enhanced PEC stability (91.3%), which prevented photocorrosion. Finally, a proposed PEC mechanism of ZNR@Gr/AuPd was illustrated to explain the charge transfer and the role of graphene and AuPd nanoparticles in the improvement of PEC performance and stability. The ZNR@Gr/AuPd electrode shows excellent PEC performance and stability, exhibiting promising potential in the generation of H-2. |
WOS研究方向 | Chemistry |
语种 | 英语 |
出版者 | ROYAL SOC CHEMISTRY |
源URL | [http://ir.sic.ac.cn/handle/331005/27386] ![]() |
专题 | 中国科学院上海硅酸盐研究所 |
推荐引用方式 GB/T 7714 | Zhang, Yuzhi,Zhang, Yunlong,Guo, Yunfeng,et al. Synthesis of AuPd nanoparticle-decorated graphene-coated ZnO nanorod arrays with enhanced photoelectrochemical performance and stability[J]. RSC ADVANCES,2019,9(5):2666. |
APA | Zhang, Yuzhi,Zhang, Yunlong,Guo, Yunfeng,Wu, Lingnan,Liu, Yangqiao,&Song, Lixing.(2019).Synthesis of AuPd nanoparticle-decorated graphene-coated ZnO nanorod arrays with enhanced photoelectrochemical performance and stability.RSC ADVANCES,9(5),2666. |
MLA | Zhang, Yuzhi,et al."Synthesis of AuPd nanoparticle-decorated graphene-coated ZnO nanorod arrays with enhanced photoelectrochemical performance and stability".RSC ADVANCES 9.5(2019):2666. |
入库方式: OAI收割
来源:上海硅酸盐研究所
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