In Situ Conversion of Cu3P Nanowires to Mixed Ion/Electron-Conducting Skeleton for Homogeneous Lithium Deposition
文献类型：期刊论文
| 作者 | Sun, Changzhi; Lin, Aming; Li, Wenwen; Jin, Jun; Sun, Yiyang; Yang, Jianhua; Wen, Zhaoyin |
| 刊名 | ADVANCED ENERGY MATERIALS
 |
| 出版日期 | 2019-12-31 |
| 关键词 | Cu3P nanowires in situ conversion Li-metal batteries lithium deposition behavior mixed ion electron conductors |
| ISSN号 | 1614-6832 |
| DOI | 10.1002/aenm.201902989 |
| 文献子类 | Article; Early Access |
| 英文摘要 | The introduction of 3D wettable current collectors is one of the practical strategies toward realizing high reversibility of lithium (Li) metal anodes, yet its effect is usually insufficient owing to single electron-conductive skeleton. Here, homogeneous Li deposition behavior and enhanced Coulombic efficiency is reported for electrochemically lithiated Cu3P nanowires, owing to the formation of a mixed ion/electron-conducting skeleton (MIECS). In particular, by evaluating the Gibbs free energy change, the possible chemical reaction between Cu3P and molten Li is used to construct a MIECS containing Li3P and Cu-Li alloy phase. The successful conversion of Cu3P nanowires to Li3P and Cu-Li alloy nanocomposite not only greatly reduces the surface energy between molten Li and Cu3P, but also induces uniform Li stripping/plating behavior via balanced ion/electron transport. Thus, the as-obtained Li@MIECS composite anode displays superior cycling stability in both symmetric cells and full cells. This work provides a promising option for the preparation of high-performance composite Li anodes containing MIECS by thermally pre-storing Li. |
| WOS关键词 | METAL ANODE ; ELECTRODEPOSITION ; INTERPHASE ; NUCLEATION ; BATTERY ; STORAGE ; UNIFORM ; FACILE |
| WOS研究方向 | Chemistry ; Energy & Fuels ; Materials Science ; Physics |
| 语种 | 英语 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| 源URL | [http://ir.sic.ac.cn/handle/331005/27479]  |
| 专题 | 中国科学院上海硅酸盐研究所 |
| 推荐引用方式 GB/T 7714 | Sun, Changzhi,Lin, Aming,Li, Wenwen,et al. In Situ Conversion of Cu3P Nanowires to Mixed Ion/Electron-Conducting Skeleton for Homogeneous Lithium Deposition[J]. ADVANCED ENERGY MATERIALS,2019. |
| APA | Sun, Changzhi.,Lin, Aming.,Li, Wenwen.,Jin, Jun.,Sun, Yiyang.,...&Wen, Zhaoyin.(2019).In Situ Conversion of Cu3P Nanowires to Mixed Ion/Electron-Conducting Skeleton for Homogeneous Lithium Deposition.ADVANCED ENERGY MATERIALS. |
| MLA | Sun, Changzhi,et al."In Situ Conversion of Cu3P Nanowires to Mixed Ion/Electron-Conducting Skeleton for Homogeneous Lithium Deposition".ADVANCED ENERGY MATERIALS (2019). |
入库方式： OAI收割
来源：上海硅酸盐研究所
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