Efficient and Stable Inverted Perovskite Solar Cells Incorporating Secondary Amines
文献类型：期刊论文
| 作者 | Chen, Hao; Wei, Qi; Saidaminov, Makhsud, I; Wang, Fei; Johnston, Andrew; Hou, Yi; Peng, Zijian; Xu, Kaimin; Zhou, Wenjia; Liu, Zhenghao |
| 刊名 | ADVANCED MATERIALS
 |
| 出版日期 | 2019-11-30 |
| 卷号 | 31期号:46 |
| 关键词 | defect density inverted structure perovskite solar cells secondary amine stability |
| ISSN号 | 0935-9648 |
| DOI | 10.1002/adma.201903559 |
| 文献子类 | Article |
| 英文摘要 | Large-bandgap perovskites offer a route to improve the efficiency of energy capture in photovoltaics when employed in the front cell of perovskite-silicon tandems. Implementing perovskites as the front cell requires an inverted (p-i-n) architecture; this architecture is particularly effective at harnessing high-energy photons and is compatible with ionic-dopant-free transport layers. Here, a power conversion efficiency of 21.6% is reported, the highest among inverted perovskite solar cells (PSCs). Only by introducing a secondary amine into the perovskite structure to form MA(1-)(x)DMA(x)PbI(3) (MA is methylamine and DMA is dimethylamine) are defect density and carrier recombination suppressed to enable record performance. It is also found that the controlled inclusion of DMA increases the hydrophobicity and stability of films in ambient operating conditions: encapsulated devices maintain over 80% of their efficiency following 800 h of operation at the maximum power point, 30 times longer than reported in the best prior inverted PSCs. The unencapsulated devices show record operational stability in ambient air among PSCs. |
| WOS关键词 | TOTAL-ENERGY CALCULATIONS ; HYBRID ; CONVERSION ; TRANSPORT ; LAYERS |
| WOS研究方向 | Chemistry ; Science & Technology - Other Topics ; Materials Science ; Physics |
| 语种 | 英语 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| 源URL | [http://ir.sic.ac.cn/handle/331005/27531]  |
| 专题 | 中国科学院上海硅酸盐研究所 |
| 推荐引用方式 GB/T 7714 | Chen, Hao,Wei, Qi,Saidaminov, Makhsud, I,et al. Efficient and Stable Inverted Perovskite Solar Cells Incorporating Secondary Amines[J]. ADVANCED MATERIALS,2019,31(46). |
| APA | Chen, Hao.,Wei, Qi.,Saidaminov, Makhsud, I.,Wang, Fei.,Johnston, Andrew.,...&Ning, Zhijun.(2019).Efficient and Stable Inverted Perovskite Solar Cells Incorporating Secondary Amines.ADVANCED MATERIALS,31(46). |
| MLA | Chen, Hao,et al."Efficient and Stable Inverted Perovskite Solar Cells Incorporating Secondary Amines".ADVANCED MATERIALS 31.46(2019). |
入库方式： OAI收割
来源：上海硅酸盐研究所
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