Syntheses, crystal structures and properties of Zn(II) and Cd(II) complexes derived from N-(o-nitrophenyl)-N '-(methoxycarbonyl)thiourea(H(2)omt) and 2,2 '-bipyridine(bpy) or o-phenanthroline(phen)
文献类型：期刊论文
| 作者 | Shen, X ; Shi, XF; Kang, BS; Liu, Y; Tong, YX; Jiang, HL; Chen, KX
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| 刊名 | POLYHEDRON
 |
| 出版日期 | 1998 |
| 卷号 | 17期号:23-24页码:4049-4058 |
| 关键词 | syntheses crystal structures cadmium(II) complex zinc(II) complex N '-(o-nitrophenyl)-N '-(methoxycarbonyl)thiourea bipyridine o-phenanthroline |
| ISSN号 | 0277-5387 |
| DOI | 10.1016/S0277-5387(98)00208-3 |
| 文献子类 | Article |
| 英文摘要 | The chelating properties of N-(o-nitrophenyl)-N'-(methoxycarbonyl)th (H(2)omt) were investigated through the study of the crystal structures of Cd(Homt)(2)(bpy), 1, Zn(Homt)(2)(phen), 2 and H(2)omt (bpy = 2,2'-bipyridine, phen = o-phenanthroline). The cadmium(II) ion in 1 is in a distorted octahedral geometry contributed by the two N atoms from bipyridine and the two S and the two deprotonated amine N atoms from two Homt groups [Cd-N(bpy)= 2.329(3), Cd-N(amine)= 2.360(3) and Cd-S = 2.690(1) Angstrom]. The Zn(II) ion in complex 2 is four-coordinated by the two N atoms from the o-phenanthroline and the two deprotonated amine N atoms from two Homt groups in a distorted tetrahedral fashion, in which the binding of S atom to the metal is not involved [Zn-N(phen)= 2.088(4), Zn-N(amine)= 1.998(3) Angstrom]. (C) 1998 Elsevier Science Ltd. All rights reserved. |
| WOS关键词 | ELECTROCHEMICAL SYNTHESIS ; COBALT COMPLEXES ; COPPER ; CADMIUM(II) ; THIOUREAS ; BINDING ; NICKEL |
| WOS研究方向 | Chemistry ; Crystallography |
| 语种 | 英语 |
| WOS记录号 | WOS:000077509600009 |
| 出版者 | PERGAMON-ELSEVIER SCIENCE LTD |
| 源URL | [http://119.78.100.183/handle/2S10ELR8/274878]  |
| 专题 | 中国科学院上海药物研究所 |
| 通讯作者 | Shen, X |
| 作者单位 | 1.Tongji Univ, Dept Chem, Shanghai 200092, Peoples R China 2.Chinese Acad Sci, Shanghai Inst Mat Med, Shanghai 200031, Peoples R China 3.Zhongshan Univ, Dept Chem, Guangzhou 510275, Peoples R China |
| 推荐引用方式 GB/T 7714 | Shen, X,Shi, XF,Kang, BS,et al. Syntheses, crystal structures and properties of Zn(II) and Cd(II) complexes derived from N-(o-nitrophenyl)-N '-(methoxycarbonyl)thiourea(H(2)omt) and 2,2 '-bipyridine(bpy) or o-phenanthroline(phen)[J]. POLYHEDRON,1998,17(23-24):4049-4058. |
| APA | Shen, X.,Shi, XF.,Kang, BS.,Liu, Y.,Tong, YX.,...&Chen, KX.(1998).Syntheses, crystal structures and properties of Zn(II) and Cd(II) complexes derived from N-(o-nitrophenyl)-N '-(methoxycarbonyl)thiourea(H(2)omt) and 2,2 '-bipyridine(bpy) or o-phenanthroline(phen).POLYHEDRON,17(23-24),4049-4058. |
| MLA | Shen, X,et al."Syntheses, crystal structures and properties of Zn(II) and Cd(II) complexes derived from N-(o-nitrophenyl)-N '-(methoxycarbonyl)thiourea(H(2)omt) and 2,2 '-bipyridine(bpy) or o-phenanthroline(phen)".POLYHEDRON 17.23-24(1998):4049-4058. |
入库方式： OAI收割
来源：上海药物研究所
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