Copper(I)-Catalyzed Decarboxylative Coupling of Propiolic Acids with Secondary Amines and Aldehydes
文献类型：期刊论文
| 作者 | Ermolat'ev, Denis S.2; Feng, Huangdi1,2; Song, Gonghua3; Van der Eycken, Erik V.2 |
| 刊名 | EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
 |
| 出版日期 | 2014-08 |
| 期号 | 24页码:5346-5350 |
| 关键词 | C-C coupling Microwave chemistry Multicomponent reactions Synthetic methods Propargylation |
| ISSN号 | 1434-193X |
| DOI | 10.1002/ejoc.201402338 |
| 文献子类 | Article |
| 英文摘要 | An efficient microwave-assisted synthesis of tertiary propargylamines has been developed by copper(I)-catalyzed decarboxylative A(3)-coupling reaction of an alkynylcarboxylic acid with a secondary amine and an aldehyde. A wide range of diversely substituted propargylamines could be synthesized in high yields. The optimal reaction conditions are also effective for 3-alkylpropiolic acids and for terminal propiolic acid. |
| WOS关键词 | C-H ACTIVATION ; HIGHLY ENANTIOSELECTIVE SYNTHESIS ; COMPLEX-CATALYZED SYNTHESIS ; POT 3-COMPONENT SYNTHESIS ; SOLVENT-FREE CONDITIONS ; SELECTIVE SYNTHESIS ; EFFICIENT SYNTHESIS ; TERMINAL ALKYNES ; DIRECT ADDITION ; PROPARGYLAMINES |
| 资助项目 | Fund for Scientific Research - Flanders, Belgium (F. W. O.)[00000000] ; Katholieke Universiteit Leuven[00000000] ; Industrial Research Fund of the Katholieke Universiteit Leuven[00000000] ; China Scholarship Council[00000000] |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000340525300021 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| 源URL | [http://119.78.100.183/handle/2S10ELR8/276962]  |
| 专题 | 中国科学院上海药物研究所 |
| 通讯作者 | Van der Eycken, Erik V. |
| 作者单位 | 1.Chinese Acad Sci, Chinese Natl Compound Lib, Shanghai Inst Mat Med, Shanghai 201203, Peoples R China; 2.Katholieke Univ Leuven, LOMAC, Dept Chem, B-3001 Leuven, Belgium; 3.E China Univ Sci & Technol, Shanghai Key Lab Chem Biol, Shanghai 200237, Peoples R China |
| 推荐引用方式 GB/T 7714 | Ermolat'ev, Denis S.,Feng, Huangdi,Song, Gonghua,et al. Copper(I)-Catalyzed Decarboxylative Coupling of Propiolic Acids with Secondary Amines and Aldehydes[J]. EUROPEAN JOURNAL OF ORGANIC CHEMISTRY,2014(24):5346-5350. |
| APA | Ermolat'ev, Denis S.,Feng, Huangdi,Song, Gonghua,&Van der Eycken, Erik V..(2014).Copper(I)-Catalyzed Decarboxylative Coupling of Propiolic Acids with Secondary Amines and Aldehydes.EUROPEAN JOURNAL OF ORGANIC CHEMISTRY(24),5346-5350. |
| MLA | Ermolat'ev, Denis S.,et al."Copper(I)-Catalyzed Decarboxylative Coupling of Propiolic Acids with Secondary Amines and Aldehydes".EUROPEAN JOURNAL OF ORGANIC CHEMISTRY .24(2014):5346-5350. |
入库方式： OAI收割
来源：上海药物研究所
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