Hydrolysis of AlLi/NaBH4 system promoted by Co powder with different particle size and amount as synergistic hydrogen generation for portable fuel cell
文献类型：期刊论文
| 作者 | Fan, Mei Qiang1; Wang, Yu1; Tian, Guang Lei1; Mei, De Sheng2; Chen, Da1; Shu, Kang Yin1 |
| 刊名 | INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
 |
| 出版日期 | 2013-08-21 |
| 卷号 | 38期号:25页码:10857-10863 |
| 关键词 | Hydrogen generation Co-based catalyst Al-Li-Co/NaBH4 system |
| ISSN号 | 0360-3199 |
| DOI | 10.1016/j.ijhydene.2013.02.051 |
| 文献子类 | Article; Proceedings Paper |
| 英文摘要 | Hydrogen generation from the hydrolysis of aluminum lithium/sodium borohydride (referred to as AlLi/NaBH4) system activated by Co powder with different particle size and amount was evaluated in this paper. The designed aluminum-lithium-cobalt (referred to as Al-Li-Co/NaBH4) systems including Al-5 wt% Li-50 wt% nano Co, Al-7.5 wt% Li-25 wt% nano Co, Al-5 wt% Li-50 wt% micro Co, and Al-7.5 wt% Li-25 wt% micro Co had 100% hydrogen yield at 323 K. The hydrogen generation rates of these systems were regulated by Co species, Co amount, as well as consecutive runs of NaBH4 hydrolysis. The underlying activation mechanism, including the formation of Al0.94Co1.06 alloy and highly active and stable Co-based catalyst has been elaborated in this study. Experimental data present an inexpensive and highly efficient hydrogen source for portable fuel cell. Copyright (C) 2013, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved. |
| WOS关键词 | SODIUM-BOROHYDRIDE HYDROLYSIS ; CATALYSTS ; ALUMINUM ; NABH4 |
| WOS研究方向 | Chemistry ; Electrochemistry ; Energy & Fuels |
| 语种 | 英语 |
| WOS记录号 | WOS:000324563100083 |
| 出版者 | PERGAMON-ELSEVIER SCIENCE LTD |
| 源URL | [http://119.78.100.183/handle/2S10ELR8/277500]  |
| 专题 | 中国科学院上海药物研究所 |
| 通讯作者 | Fan, Mei Qiang |
| 作者单位 | 1.China Jiliang Univ, Dept Mat Sci & Engn, Hangzhou 310018, Zhejiang, Peoples R China; 2.Chinese Acad Sci, Shanghai Inst Mat Med, Dept Med Chem, Shanghai 201203, Peoples R China |
| 推荐引用方式 GB/T 7714 | Fan, Mei Qiang,Wang, Yu,Tian, Guang Lei,et al. Hydrolysis of AlLi/NaBH4 system promoted by Co powder with different particle size and amount as synergistic hydrogen generation for portable fuel cell[J]. INTERNATIONAL JOURNAL OF HYDROGEN ENERGY,2013,38(25):10857-10863. |
| APA | Fan, Mei Qiang,Wang, Yu,Tian, Guang Lei,Mei, De Sheng,Chen, Da,&Shu, Kang Yin.(2013).Hydrolysis of AlLi/NaBH4 system promoted by Co powder with different particle size and amount as synergistic hydrogen generation for portable fuel cell.INTERNATIONAL JOURNAL OF HYDROGEN ENERGY,38(25),10857-10863. |
| MLA | Fan, Mei Qiang,et al."Hydrolysis of AlLi/NaBH4 system promoted by Co powder with different particle size and amount as synergistic hydrogen generation for portable fuel cell".INTERNATIONAL JOURNAL OF HYDROGEN ENERGY 38.25(2013):10857-10863. |
入库方式： OAI收割
来源：上海药物研究所
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