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Catalytic and catalyst-free diboration of alkynes

文献类型：期刊论文

作者Zhao, Fei2; Jia, Xiuwen2; Li, Pinyi2; Zhao, Jingwei2; Zhou, Yu1,3,4; Wang, Jiang1,3,4; Liu, Hong1,3,4
刊名ORGANIC CHEMISTRY FRONTIERS
出版日期2017-11-01
卷号4期号:11页码:2235-2255
ISSN号2052-4129
DOI10.1039/c7qo00614d
文献子类Review
英文摘要The diboration of alkynes has become the most straightforward and powerful method for the synthesis of functionalized 1,2-diborylalkenes, which are widely used as building blocks in organic synthesis. The present review provides a comprehensive summary of the diboration of alkynes, including platinum-, palladium-, cobalt-, copper-, iridium-, gold-, iron-, base- and small organic molecule-catalyzed diboration, direct and metal-free diboration, and base- promoted diboration of alkynes up to early 2017. The reaction conditions, regio- and stereoselectivities, and mechanisms are summarized in detail. Moreover, synthetic applications and perspectives on the diboration of alkynes are also discussed.
WOS关键词C-H BORYLATION ; UNSATURATED ORGANIC-MOLECULES ; CROSS-COUPLING REACTIONS ; TERMINAL ALKYNES ; DEHYDROGENATIVE BORYLATION ; ASYMMETRIC DIHYDROXYLATION ; PLATINUM NANOPARTICLES ; DIBORON TETRACHLORIDE ; EFFICIENT SYNTHESIS ; BORON-BORON
资助项目National Natural Science Foundation of China[21602022] ; National Natural Science Foundation of China[81620108027] ; National Natural Science Foundation of China[21632008] ; Major Project of Chinese National Programs for Fundamental Research and Development[2015CB910304] ; Open Project Program of Key Laboratory of Medicinal and Edible Plants Resources Development of Sichuan Education Department[10Y201711]
WOS研究方向Chemistry
语种英语
WOS记录号WOS:000413826400029
出版者ROYAL SOC CHEMISTRY
源URL[http://119.78.100.183/handle/2S10ELR8/272434]  
专题药物化学研究室
中科院受体结构与功能重点实验室
新药研究国家重点实验室
通讯作者Liu, Hong
作者单位1.Chinese Acad Sci, Shanghai Inst Mat Med, CAS Key Lab Receptor Res, 555 Zu Chong Zhi Rd, Shanghai 201203, Peoples R China;
2.Chengdu Univ, Antibiot Res & Reevaluat Key Lab Sichuan Prov, Sichuan Ind Inst Antibiot, 168 Hua Guan Rd, Chengdu 610052, Sichuan, Peoples R China;
3.Chinese Acad Sci, State Key Lab Drug Res, Shanghai Inst Mat Med, 555 Zu Chong Zhi Rd, Shanghai 201203, Peoples R China;
4.Univ Chinese Acad Sci, 19A Yuquan Rd, Beijing 100049, Peoples R China
推荐引用方式
GB/T 7714		 Zhao, Fei,Jia, Xiuwen,Li, Pinyi,et al. Catalytic and catalyst-free diboration of alkynes[J]. ORGANIC CHEMISTRY FRONTIERS,2017,4(11):2235-2255.
APA Zhao, Fei.,Jia, Xiuwen.,Li, Pinyi.,Zhao, Jingwei.,Zhou, Yu.,...&Liu, Hong.(2017).Catalytic and catalyst-free diboration of alkynes.ORGANIC CHEMISTRY FRONTIERS,4(11),2235-2255.
MLA Zhao, Fei,et al."Catalytic and catalyst-free diboration of alkynes".ORGANIC CHEMISTRY FRONTIERS 4.11(2017):2235-2255.

入库方式： OAI收割

来源：上海药物研究所

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