Natural occurrence of all eight stereoisomers of a neosecurinane structure from Flueggea virosa
文献类型：期刊论文
| 作者 | Zhang, Hua; Zhu, Kong-Kai; Gao, Xin-Hua; Yue, Jian-Min
|
| 刊名 | TETRAHEDRON
 |
| 出版日期 | 2017-08-03 |
| 卷号 | 73期号:31页码:4692-4697 |
| 关键词 | Flueggea virosa Securinega alkaloids Natural enantiomers |
| ISSN号 | 0040-4020 |
| DOI | 10.1016/j.tet.2017.06.035 |
| 文献子类 | Article |
| 英文摘要 | All eight stereoisomers (1-8) of a neosecurinane-type Securinega alkaloid were isolated and identified from a Chinese medicinal plant, Flueggea virosa. Structures of the four pairs of enantiomers were characterized and differentiated from one another based on comprehensive spectroscopic analyses especially specific optical rotation and electronic circular dichroism measurements. While clarifying some historical ambiguities, the discovery of these molecules also brings new puzzles to the natural products community, which will be surely leading to further attention and studies. This case investigation also reminds that future researchers who work with natural products should pay more attention to the enantiomeric purity of their samples. (C) 2017 Elsevier Ltd. All rights reserved. |
| WOS关键词 | SECURINEGA-SUFFRUTICOSA ; ALKALOIDS ; PRODUCTS ; REHD |
| 资助项目 | National Natural Science Foundation[81322045] |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000405977600024 |
| 出版者 | PERGAMON-ELSEVIER SCIENCE LTD |
| 源URL | [http://119.78.100.183/handle/2S10ELR8/272532]  |
| 专题 | 天然药物化学研究室 中科院受体结构与功能重点实验室 期刊编辑部 新药研究国家重点实验室 分析化学研究室 |
| 通讯作者 | Yue, Jian-Min |
| 作者单位 | Chinese Acad Sci, Shanghai Inst Mat Med, State Key Lab Drug Res, 555 Zu Chong Zhi Rd,Zhangjiang Hitech Pk, Shanghai 201203, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhang, Hua,Zhu, Kong-Kai,Gao, Xin-Hua,et al. Natural occurrence of all eight stereoisomers of a neosecurinane structure from Flueggea virosa[J]. TETRAHEDRON,2017,73(31):4692-4697. |
| APA | Zhang, Hua,Zhu, Kong-Kai,Gao, Xin-Hua,&Yue, Jian-Min.(2017).Natural occurrence of all eight stereoisomers of a neosecurinane structure from Flueggea virosa.TETRAHEDRON,73(31),4692-4697. |
| MLA | Zhang, Hua,et al."Natural occurrence of all eight stereoisomers of a neosecurinane structure from Flueggea virosa".TETRAHEDRON 73.31(2017):4692-4697. |
入库方式： OAI收割
来源：上海药物研究所
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