Sensitized photooxidation of furanoeremophilane with singlet oxygen and their biogenetic relationship
文献类型：期刊论文
| 作者 | Li, YS; Wang, ZT; Luo, SD; Li, SS; Zhu, DY |
| 刊名 | NATURAL PRODUCT RESEARCH
 |
| 出版日期 | 2006-07-10 |
| 卷号 | 20期号:8页码:724-730 |
| 关键词 | furanoeremophilane photosensitized oxidation biogenetic relationship structure-activity relationship |
| ISSN号 | 1478-6419 |
| DOI | 10.1080/14786410500185733 |
| 文献子类 | Article |
| 英文摘要 | In an attempt to explore the biogenetic relationship of furanoeremophilane derivatives and eremophilan-8 alpha, 12-olides, produced in Ligularia and their structure-activity relationship, we studied the photosensitized oxidation of furanoeremophilane - type sesquiterpenes. Under the condition of several solvents solution Irradiation with a 200 W incandescent lamp of furanoeremophilan-14 beta,6 alpha-olide isolated from Ligularia vellerea, in various solutions with methylene blue, rose bengal, toluidine blue and safranine T gave several products. The products were isolated by chromatographic procedure and their structures were elucidated as eremophilan-14 beta,6 alpha,8 alpha,12-diolide derivatives by NMR, IR and MS methods. A reaction mechanism has been proposed. |
| WOS研究方向 | Chemistry ; Pharmacology & Pharmacy |
| 语种 | 英语 |
| WOS记录号 | WOS:000238074900005 |
| 出版者 | TAYLOR & FRANCIS LTD |
| 源URL | [http://119.78.100.183/handle/2S10ELR8/273542]  |
| 专题 | 新药研究国家重点实验室 中科院受体结构与功能重点实验室 |
| 通讯作者 | Li, YS |
| 作者单位 | 1.Chinese Acad Sci, Inst Mat Med, State Key Lab Drug Res, Shanghai 201203, Peoples R China 2.Shanghai Jiao Tong Univ, Sch Pharm, Dept Nat Med Chem, Shanghai 201203, Peoples R China 3.China Pharmaceut Univ, Dept Pharmacognosy, Nanjing 210038, Peoples R China 4.Chinese Acad Sci, Kunming Inst Bot, Kunming 650204, Peoples R China |
| 推荐引用方式 GB/T 7714 | Li, YS,Wang, ZT,Luo, SD,et al. Sensitized photooxidation of furanoeremophilane with singlet oxygen and their biogenetic relationship[J]. NATURAL PRODUCT RESEARCH,2006,20(8):724-730. |
| APA | Li, YS,Wang, ZT,Luo, SD,Li, SS,&Zhu, DY.(2006).Sensitized photooxidation of furanoeremophilane with singlet oxygen and their biogenetic relationship.NATURAL PRODUCT RESEARCH,20(8),724-730. |
| MLA | Li, YS,et al."Sensitized photooxidation of furanoeremophilane with singlet oxygen and their biogenetic relationship".NATURAL PRODUCT RESEARCH 20.8(2006):724-730. |
入库方式： OAI收割
来源：上海药物研究所
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