New eremophilane-type sesquiterpenes from Ligularia lapathifolia
文献类型：期刊论文
| 作者 | Li, YS; Wang, ZT; Zhang, M ; Zhou, H; Chen, JJ; Lu, SD
|
| 刊名 | PLANTA MEDICA
 |
| 出版日期 | 2004-03 |
| 卷号 | 70期号:3页码:239-243 |
| 关键词 | Ligularia lapathifolia Asteraceae eremophilane-type sesquiterpenes photooxygenation |
| ISSN号 | 0032-0943 |
| DOI | 10.1055/s-2004-815541 |
| 文献子类 | Article |
| 英文摘要 | Seven new eremophilanolides were isolated from the roots and rhizomes of Ligularia lapathifolia. Their structures were established as 3beta-angeloyloxy-8betaH-eremophil-7(11)-ene-12,8alpha(14beta,6alpha)-diolide, 3beta-angeloyloxy-8beta-hydroxyeremophil-7(11)-ene-12,8alpha(14beta,6alpha)-diolide,3beta-angeloyloxy-8beta-methoxyeremophil-7(11)-ene-12,8alpha(14beta,6alpha)-diolide,3beta-angeloyloxy-8beta -ethoxyeremophil-7(11)-ene-12,8alpha (14beta,6alpha)-diolide, 3beta-angeloyloxy-10beta-hydroxyeremophil-8(9),7(11)-diene-12,8(14beta,6alpha)-diolide, 3beta-angeloyloxy-8,12-expoy-12alpha-hydroxy-8beta-methoxyeremophil-7(11)-en-14beta,6alpha-olide and 3beta-angeloyloxyeremophilan-7,11-dien-14beta,6alpha-olide, by means of spectroscopic analyses. Moreover, application of a photooxygenation reaction on 7 resulted in the generation of 2 with an alpha,beta-unsaturated gamma-lactone moiety. This biomimetic transformation supports a biogenetic pathway proposed for 2. |
| WOS关键词 | OXYGENATION ; FURANS |
| WOS研究方向 | Plant Sciences ; Pharmacology & Pharmacy ; Integrative & Complementary Medicine |
| 语种 | 英语 |
| WOS记录号 | WOS:000220573600009 |
| 出版者 | GEORG THIEME VERLAG KG |
| 源URL | [http://119.78.100.183/handle/2S10ELR8/274113]  |
| 专题 | 天然药物化学研究室 中科院受体结构与功能重点实验室 新药研究国家重点实验室 |
| 通讯作者 | Li, YS |
| 作者单位 | 1.Chinese Acad Sci, Kunming Inst Bot, Kunming, Peoples R China 2.Chinese Acad Sci, Shanghai Inst Mat Med, State Key Lab Drug Res, Shanghai 201203, Peoples R China 3.China Pharmaceut Univ, Dept Pharmacognosy, Nanjing, Peoples R China |
| 推荐引用方式 GB/T 7714 | Li, YS,Wang, ZT,Zhang, M,et al. New eremophilane-type sesquiterpenes from Ligularia lapathifolia[J]. PLANTA MEDICA,2004,70(3):239-243. |
| APA | Li, YS,Wang, ZT,Zhang, M,Zhou, H,Chen, JJ,&Lu, SD.(2004).New eremophilane-type sesquiterpenes from Ligularia lapathifolia.PLANTA MEDICA,70(3),239-243. |
| MLA | Li, YS,et al."New eremophilane-type sesquiterpenes from Ligularia lapathifolia".PLANTA MEDICA 70.3(2004):239-243. |
入库方式： OAI收割
来源：上海药物研究所
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