Palhicerines A-F, Lycopodium alkaloids from the club moss Palhinhaea cernua
文献类型：期刊论文
| 作者 | Tang, Yu1; Xiong, Juan1; Zou, Yike2; Zhang, Hai-Yan3 ; Hu, Jin-Feng1
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| 刊名 | PHYTOCHEMISTRY
 |
| 出版日期 | 2016-11 |
| 卷号 | 131页码:130-139 |
| 关键词 | Palhinhaea cernua Lycopodiaceae Lycopodium alkaloids Palhicerines |
| ISSN号 | 0031-9422 |
| DOI | 10.1016/j.phytochem.2016.08.010 |
| 文献子类 | Article |
| 英文摘要 | Four fawcettimine-type (palhicerines A-D, resp.) and two lycopodine-type (palhicerines E and F) Lycopodium alkaloids together with twenty known ones were isolated from the whole plant of Palhinhaea cernua. The structures and absolute configurations of the palhicerines A-F were determined by extensive spectroscopic methods, single-crystal X-ray diffraction analyses, chemical transformation, and electronic circular dichroism (ECD) calculations or induced electronic circular dichroism (IECD) spectra. Among the isolates, the new CID-ring of the palhicerines A-C (trans-fused fawcettimine-type alkaloids) are rare, and each possesses a a-oriented C-16 methyl group and a distinctive tertiary methoxy group at C-13. Chemotaxonomy for differentiating species in the genus Palhinhaea is briefly discussed. (C) 2016 Elsevier Ltd. All rights reserved. |
| WOS关键词 | FAWCETTIMINE-RELATED ALKALOIDS ; HUPERZIA-SERRATA ; ABSOLUTE-CONFIGURATION ; DIPHASIASTRUM ; ASSIGNMENT ; CLASSIFICATION ; MO-2(OAC)(4) ; 1,2-DIOLS ; SKELETON ; OBSCURUM |
| 资助项目 | NSFC[21472021] ; NSFC[81273401] ; NSFC[81202420] ; National Basic Research Program of China (973 Program)[2013CB530700] |
| WOS研究方向 | Biochemistry & Molecular Biology ; Plant Sciences |
| 语种 | 英语 |
| WOS记录号 | WOS:000385692000015 |
| 出版者 | PERGAMON-ELSEVIER SCIENCE LTD |
| 源URL | [http://119.78.100.183/handle/2S10ELR8/275843]  |
| 专题 | 药理学第二研究室 中科院受体结构与功能重点实验室 新药研究国家重点实验室 |
| 通讯作者 | Xiong, Juan; Hu, Jin-Feng |
| 作者单位 | 1.Fudan Univ, Sch Pharm, Dept Nat Prod Chem, 826 Zhangheng Rd, Shanghai 201203, Peoples R China; 2.Univ Penn, Dept Chem, 231 S 34 St, Philadelphia, PA 19104 USA; 3.Chinese Acad Sci, Shanghai Inst Mat Med, State Key Lab Drug Res, 555 Zuchongzhi Rd, Shanghai 201203, Peoples R China |
| 推荐引用方式 GB/T 7714 | Tang, Yu,Xiong, Juan,Zou, Yike,et al. Palhicerines A-F, Lycopodium alkaloids from the club moss Palhinhaea cernua[J]. PHYTOCHEMISTRY,2016,131:130-139. |
| APA | Tang, Yu,Xiong, Juan,Zou, Yike,Zhang, Hai-Yan,&Hu, Jin-Feng.(2016).Palhicerines A-F, Lycopodium alkaloids from the club moss Palhinhaea cernua.PHYTOCHEMISTRY,131,130-139. |
| MLA | Tang, Yu,et al."Palhicerines A-F, Lycopodium alkaloids from the club moss Palhinhaea cernua".PHYTOCHEMISTRY 131(2016):130-139. |
入库方式： OAI收割
来源：上海药物研究所
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