Humulane-type sesquiterpenoids from Pilea cavaleriei subsp crenata
文献类型:期刊论文
作者 | Liao, Cang-Song1,2; Tang, Chun-Ping1,2![]() ![]() ![]() |
刊名 | ORGANIC & BIOMOLECULAR CHEMISTRY
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出版日期 | 2013-08-07 |
卷号 | 11期号:29页码:4840-4846 |
ISSN号 | 1477-0520 |
DOI | 10.1039/c3ob40872h |
文献子类 | Article |
英文摘要 | Nine new, uncommon humulane-type sesquiterpenoids (1, 2, 4, 6-11), together with two known derivatives, were isolated from extracts of the plant Pilea cavaleriei subsp. crenate. The structures of these compounds were fully elucidated by extensive analyses of spectroscopic data (MS, 1D- and 2D-NMR), use of the Mosher method, and by X-ray crystallographic analysis, in combination with chemical conversions. An ene reaction was discovered during the chemical transformations, which might provide an explanation for the wide distribution of the allylic hydroperoxide group in natural products. |
WOS关键词 | NATURAL SESQUITERPENOIDS |
资助项目 | National Science & Technology Major Project "Key New Drug Creation and Manufacturing Program"[2011ZX09307-002-03] ; National Natural Science Funds for Distinguished Young Scholar[30925043] ; Ministry of Science and Technology[2007DFC31030] ; Ministry of Science and Technology[2010DFA30980] ; Shanghai Commission of Science and Technology[10DZ1972700] ; Shanghai Commission of Science and Technology[11DZ1970700] ; Shanghai Commission of Science and Technology[12JC1410300] |
WOS研究方向 | Chemistry |
语种 | 英语 |
WOS记录号 | WOS:000322299100013 |
出版者 | ROYAL SOC CHEMISTRY |
源URL | [http://119.78.100.183/handle/2S10ELR8/277509] ![]() |
专题 | 天然药物化学研究室 中科院受体结构与功能重点实验室 新药研究国家重点实验室 |
通讯作者 | Ye, Yang |
作者单位 | 1.Chinese Acad Sci, State Key Lab Drug Res, Shanghai 201203, Peoples R China; 2.Chinese Acad Sci, Dept Nat Prod Chem, Shanghai Inst Mat Med, Shanghai 201203, Peoples R China |
推荐引用方式 GB/T 7714 | Liao, Cang-Song,Tang, Chun-Ping,Yao, Sheng,et al. Humulane-type sesquiterpenoids from Pilea cavaleriei subsp crenata[J]. ORGANIC & BIOMOLECULAR CHEMISTRY,2013,11(29):4840-4846. |
APA | Liao, Cang-Song,Tang, Chun-Ping,Yao, Sheng,&Ye, Yang.(2013).Humulane-type sesquiterpenoids from Pilea cavaleriei subsp crenata.ORGANIC & BIOMOLECULAR CHEMISTRY,11(29),4840-4846. |
MLA | Liao, Cang-Song,et al."Humulane-type sesquiterpenoids from Pilea cavaleriei subsp crenata".ORGANIC & BIOMOLECULAR CHEMISTRY 11.29(2013):4840-4846. |
入库方式: OAI收割
来源:上海药物研究所
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