Gold-catalyzed Reactions of 3-Alkynyloxireno[2, 3-b]chromenones to Form 3(2H)-Furanones via a Domino Pathway
文献类型：期刊论文
| 作者 | Hu, Feng; Yan, Jianwei; Cheng, Ming; Hu, Youhong
|
| 刊名 | CHEMISTRY-AN ASIAN JOURNAL
 |
| 出版日期 | 2013-02 |
| 卷号 | 8期号:2页码:482-487 |
| 关键词 | furanones domino reactions gold nucleophilic addition oxidation |
| ISSN号 | 1861-4728 |
| DOI | 10.1002/asia.201200974 |
| 文献子类 | Article |
| 英文摘要 | 3(2H)-Furanones are efficiently generated from 3-alkynyl oxireno[2,3-b]chromenones by an Au/DDQ-catalyzed domino reaction through a pathway composed of cyclization, C?C cleavage, nucleophilic addition, oxidation, and nucleophilic addition. It was found that stoichiometric AuCl3 or catalytic Au with stoichiometric DDQ can oxidize the benzylic sp3 C?H bond to facilitate nucleophilic addition. |
| WOS关键词 | HIGHLY SUBSTITUTED FURANS ; 2,3-DICHLORO-5,6-DICYANO-1,4-BENZOQUINONE DDQ ; EFFICIENT SYNTHESIS ; TANDEM REACTION ; KETONES ; 3-(1-ALKYNYL)CHROMONES ; CYCLOADDITION ; CONSTRUCTION ; DIVERSITY ; 2-(1-ALKYNYL)-2-ALKEN-1-ONES |
| 资助项目 | National Natural Science Foundation of China[21172232] |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000314177300021 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| 源URL | [http://119.78.100.183/handle/2S10ELR8/277748]  |
| 专题 | 药物化学研究室 中科院受体结构与功能重点实验室 新药研究国家重点实验室 |
| 通讯作者 | Hu, Youhong |
| 作者单位 | Chinese Acad Sci, State Key Lab Drug Res, Shanghai Inst Mat Med, Shanghai 201203, Peoples R China |
| 推荐引用方式 GB/T 7714 | Hu, Feng,Yan, Jianwei,Cheng, Ming,et al. Gold-catalyzed Reactions of 3-Alkynyloxireno[2, 3-b]chromenones to Form 3(2H)-Furanones via a Domino Pathway[J]. CHEMISTRY-AN ASIAN JOURNAL,2013,8(2):482-487. |
| APA | Hu, Feng,Yan, Jianwei,Cheng, Ming,&Hu, Youhong.(2013).Gold-catalyzed Reactions of 3-Alkynyloxireno[2, 3-b]chromenones to Form 3(2H)-Furanones via a Domino Pathway.CHEMISTRY-AN ASIAN JOURNAL,8(2),482-487. |
| MLA | Hu, Feng,et al."Gold-catalyzed Reactions of 3-Alkynyloxireno[2, 3-b]chromenones to Form 3(2H)-Furanones via a Domino Pathway".CHEMISTRY-AN ASIAN JOURNAL 8.2(2013):482-487. |
入库方式： OAI收割
来源：上海药物研究所
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