Structure and Absolute Stereochemistry of Nortriterpenoids from Schisandra chinensis (Turcz.) Baill
文献类型：期刊论文
| 作者 | Wang, Jian-Rong1 ; Kurtan, Tibor2; Mandi, Attila2; Guo, Yue-Wei1
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| 刊名 | EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
 |
| 出版日期 | 2012-10 |
| 期号 | 28页码:5471-5482 |
| 关键词 | Natural products Terpenoids Circular dichroism Structure elucidation Biogenetic pathway |
| ISSN号 | 1434-193X |
| DOI | 10.1002/ejoc.201200557 |
| 文献子类 | Article |
| 英文摘要 | A varierty of previously unreported compounds, the cagelike hexacyclic schicagenin-type nortriterpenoid 1, three pre-schisanartane-type nortriterpenoids 24, seven C29 nortriterpenoids 511 possessing an uncommon pentacyclic carbon skeleton characterized by a 5/5/7/7/5 fused-ring motif bearing a C9 side chain, two highly oxygenated C28 nortriterpenoids 12 and 13 containing an unprecedented 5/5/7 ring nucleus bearing a C15 side chain, and the known C29 nortriterpenoid 14 were isolated from the leaves and stems of the Chinese medicinal plant Schisandra chinensis. The structures of these new metabolites were elucidated by means of detailed spectroscopic analysis. The absolute configurations of 4 and 5 were determined by time-dependent density functional theory electronic circular dichroism (TDDFT ECD) calculations, allowing the assignment of the absolute configurations of analogous compounds 13 and 613. |
| WOS关键词 | PANDANUS-AMARYLLIFOLIUS ROXB ; LANCIFODILACTONE-G ; MICRANDILACTONE-A ; ABC RING ; SKELETON ; SCHISANARTANE ; CONSTRUCTION ; PROPINQUA ; ALKALOIDS ; SYSTEM |
| 资助项目 | Natural Science Foundation of China (NSFC)[21021063] ; Natural Science Foundation of China (NSFC)[31070310] ; Natural Science Foundation of China (NSFC)[40976048] ; SKLDR/SIMM[SIMM1203ZZ-03] ; SKLDR/SIMM[SIMM1105KF-04] ; European Social Fund[00000000] ; European Regional Development Fund[00000000] |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000308939800007 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| 源URL | [http://119.78.100.183/handle/2S10ELR8/277927]  |
| 专题 | 天然药物化学研究室 中科院受体结构与功能重点实验室 新药研究国家重点实验室 药物质量控制与固体化学研究中心 |
| 通讯作者 | Guo, Yue-Wei |
| 作者单位 | 1.Chinese Acad Sci, Shanghai Inst Mat Med, State Key Lab Drug Res, Shanghai 201203, Peoples R China; 2.Univ Debrecen, Dept Organ Chem, H-4010 Debrecen, Hungary |
| 推荐引用方式 GB/T 7714 | Wang, Jian-Rong,Kurtan, Tibor,Mandi, Attila,et al. Structure and Absolute Stereochemistry of Nortriterpenoids from Schisandra chinensis (Turcz.) Baill[J]. EUROPEAN JOURNAL OF ORGANIC CHEMISTRY,2012(28):5471-5482. |
| APA | Wang, Jian-Rong,Kurtan, Tibor,Mandi, Attila,&Guo, Yue-Wei.(2012).Structure and Absolute Stereochemistry of Nortriterpenoids from Schisandra chinensis (Turcz.) Baill.EUROPEAN JOURNAL OF ORGANIC CHEMISTRY(28),5471-5482. |
| MLA | Wang, Jian-Rong,et al."Structure and Absolute Stereochemistry of Nortriterpenoids from Schisandra chinensis (Turcz.) Baill".EUROPEAN JOURNAL OF ORGANIC CHEMISTRY .28(2012):5471-5482. |
入库方式： OAI收割
来源：上海药物研究所
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