NOVEL BIFUNCTIONAL ORGANOCATALYST USING SULFAMIDE AS HYDROGEN BONDING DONOR: APPLICATION IN ASYMMETRIC MICHAEL ADDITION OF CYCLIC KETONES TO NITROOLEFINS
文献类型：期刊论文
| 作者 | Deng, Fei1; Liu, Hong-Ying2 |
| 刊名 | SYNTHETIC COMMUNICATIONS
 |
| 出版日期 | 2012 |
| 卷号 | 42期号:5页码:767-774 |
| 关键词 | Asymmetric synthesis Michael addition organocatalysis sulfamide |
| ISSN号 | 0039-7911 |
| DOI | 10.1080/00397911.2010.531174 |
| 文献子类 | Article |
| 英文摘要 | A chiral bifunctional organocatalyst using sulfamide as novel type of hydrogen bonding donor has been developed. This catalyst was found to efficiently catalyze the Michael addition of cyclic ketones to nitroolefins in water, and the products were obtained in good yield (up to 97%), and excellent diastereoselectivities (up to >50:1) and enantioselectivities (up to 96%). |
| WOS关键词 | ALDOL REACTIONS ; THIOUREA ORGANOCATALYSTS ; PYRROLIDINE-THIOUREA ; CATALYSIS ; WATER ; ALDEHYDES ; PROLINE ; ANALOGS ; MANNICH |
| 资助项目 | State Key Laboratory of Drug Research of China[SIMM1004KF-04] ; Shanghai Committee of Science and Technology, China[11ZR1444900] |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000297980100017 |
| 出版者 | TAYLOR & FRANCIS INC |
| 源URL | [http://119.78.100.183/handle/2S10ELR8/278294]  |
| 专题 | 天然药物化学研究室 中科院受体结构与功能重点实验室 新药研究国家重点实验室 |
| 通讯作者 | Deng, Fei |
| 作者单位 | 1.Chinese Acad Sci, State Key Lab Drug Res, Shanghai Inst Mat Med, Shanghai 201203, Peoples R China; 2.NW A&F Univ, Coll Life Sci, Yangling, Shanxi, Peoples R China |
| 推荐引用方式 GB/T 7714 | Deng, Fei,Liu, Hong-Ying. NOVEL BIFUNCTIONAL ORGANOCATALYST USING SULFAMIDE AS HYDROGEN BONDING DONOR: APPLICATION IN ASYMMETRIC MICHAEL ADDITION OF CYCLIC KETONES TO NITROOLEFINS[J]. SYNTHETIC COMMUNICATIONS,2012,42(5):767-774. |
| APA | Deng, Fei,&Liu, Hong-Ying.(2012).NOVEL BIFUNCTIONAL ORGANOCATALYST USING SULFAMIDE AS HYDROGEN BONDING DONOR: APPLICATION IN ASYMMETRIC MICHAEL ADDITION OF CYCLIC KETONES TO NITROOLEFINS.SYNTHETIC COMMUNICATIONS,42(5),767-774. |
| MLA | Deng, Fei,et al."NOVEL BIFUNCTIONAL ORGANOCATALYST USING SULFAMIDE AS HYDROGEN BONDING DONOR: APPLICATION IN ASYMMETRIC MICHAEL ADDITION OF CYCLIC KETONES TO NITROOLEFINS".SYNTHETIC COMMUNICATIONS 42.5(2012):767-774. |
入库方式： OAI收割
来源：上海药物研究所
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