Recent advances in the gold-catalyzed additions to C-C multiple bonds
文献类型:期刊论文
作者 | Huang, He; Zhou, Yu![]() ![]() |
刊名 | BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY
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出版日期 | 2011-07-04 |
卷号 | 7页码:897-936 |
关键词 | asymmetric addition catalysis gold C-C multiple bonds tandem reaction |
ISSN号 | 1860-5397 |
DOI | 10.3762/bjoc.7.103 |
文献子类 | Article |
英文摘要 | C-O, C-N and C-C bonds are the most widespread types of bonds in nature, and are the cornerstone of most organic compounds, ranging from pharmaceuticals and agrochemicals to advanced materials and polymers. Cationic gold acts as a soft and carbophilic Lewis acid and is considered one of the most powerful activators of C-C multiple bonds. Consequently, gold-catalysis plays an important role in the development of new strategies to form these bonds in more convenient ways. In this review, we highlight recent advances in the gold-catalyzed chemistry of addition of X-H (X = O, N, C) bonds to C-C multiple bonds, tandem reactions, and asymmetric additions. This review covers gold-catalyzed organic reactions published from 2008 to the present. |
WOS关键词 | GOLD(I)-CATALYZED ENANTIOSELECTIVE SYNTHESIS ; REGIOSELECTIVE SYNTHESIS ; EFFICIENT SYNTHESIS ; TANDEM REACTIONS ; INTRAMOLECULAR HYDROAMINATION ; CYCLOISOMERIZATION REACTIONS ; INTERMOLECULAR REACTIONS ; NONACTIVATED ARENES ; EXPEDIENT SYNTHESIS ; MECHANISTIC ASPECTS |
资助项目 | National Natural Science Foundation of China[21021063] ; National Natural Science Foundation of China[20872153] ; National Natural Science Foundation of China[81025017] |
WOS研究方向 | Chemistry |
语种 | 英语 |
WOS记录号 | WOS:000292332900001 |
出版者 | BEILSTEIN-INSTITUT |
源URL | [http://119.78.100.183/handle/2S10ELR8/278479] ![]() |
专题 | 药物化学研究室 中科院受体结构与功能重点实验室 新药研究国家重点实验室 药物发现与设计中心 |
通讯作者 | Liu, Hong |
作者单位 | Chinese Acad Sci, State Key Lab Drug Res, Shanghai Inst Mat Med, Shanghai 201203, Peoples R China |
推荐引用方式 GB/T 7714 | Huang, He,Zhou, Yu,Liu, Hong. Recent advances in the gold-catalyzed additions to C-C multiple bonds[J]. BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY,2011,7:897-936. |
APA | Huang, He,Zhou, Yu,&Liu, Hong.(2011).Recent advances in the gold-catalyzed additions to C-C multiple bonds.BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY,7,897-936. |
MLA | Huang, He,et al."Recent advances in the gold-catalyzed additions to C-C multiple bonds".BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY 7(2011):897-936. |
入库方式: OAI收割
来源:上海药物研究所
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