Recent Advances in Silver-Mediated Organic Synthesis Reactions
文献类型：期刊论文
| 作者 | Liu Guannan1,2; Zhou Yu1 ; Jiang Hualiang1; Liu Hong1
|
| 刊名 | PROGRESS IN CHEMISTRY
 |
| 出版日期 | 2011-06 |
| 卷号 | 23期号:6页码:1137-1147 |
| 关键词 | Ag-mediate synthesis of heterocycles coupling reaction asymmetric reaction |
| ISSN号 | 1005-281X |
| 文献子类 | Article |
| 英文摘要 | The silver-catalyzed reaction is one of the frontier areas in organic chemistry, and the progress of research on it was rapid. In comparison with other transition metal salts, Ag(I) salts have long been believed to have low catalytic efficiency, and most commonly served as either co-catalysts or Lewis acids. Only recently, Ag (I) has been demonstrated to be important and versatile catalyst for a variety of organic transformations. Ag(I) is known to activate pi-systems, such as alkenes, alkynes, and allenes, towards intermolecular and intramolecular nucleophilic attacks. Moreover, efforts in studying silver-catalyzed organic transformations have focused on coupling reactions and asymmetric reactions. In addition, the use of silver (I) is economic relative to other expensive transition metals. Recent development of silver (I)-catalyzed reactions is reviewed, the substrates, reaction conditions, selectivity, yields and mechanisms are discussed and summarized. |
| WOS关键词 | CATALYZED INTRAMOLECULAR HYDROAMINATION ; ENANTIOSELECTIVE VINYLOGOUS MANNICH ; SONOGASHIRA COUPLING REACTION ; DIELS-ALDER REACTIONS ; REGIOSELECTIVE SYNTHESIS ; EFFICIENT SYNTHESIS ; TERMINAL ALKYNES ; AG(I)-CATALYZED CYCLIZATION ; CONVENIENT SYNTHESIS ; 2+2 CYCLOADDITIONS |
| WOS研究方向 | Chemistry |
| 语种 | 中文 |
| CSCD记录号 | CSCD:4217507 |
| WOS记录号 | WOS:000292342500010 |
| 出版者 | CHINESE ACAD SCIENCES |
| 源URL | [http://119.78.100.183/handle/2S10ELR8/278520]  |
| 专题 | 药物化学研究室 中科院受体结构与功能重点实验室 新药研究国家重点实验室 |
| 通讯作者 | Liu Hong |
| 作者单位 | 1.Chinese Acad Sci, Drug Discovery & Design Ctr, State Key Lab Drug Res, Shanghai Inst Mat Med, Shanghai 201203, Peoples R China; 2.China Jiliang Univ, Coll Life Sci, Hangzhou 310018, Peoples R China |
| 推荐引用方式 GB/T 7714 | Liu Guannan,Zhou Yu,Jiang Hualiang,et al. Recent Advances in Silver-Mediated Organic Synthesis Reactions[J]. PROGRESS IN CHEMISTRY,2011,23(6):1137-1147. |
| APA | Liu Guannan,Zhou Yu,Jiang Hualiang,&Liu Hong.(2011).Recent Advances in Silver-Mediated Organic Synthesis Reactions.PROGRESS IN CHEMISTRY,23(6),1137-1147. |
| MLA | Liu Guannan,et al."Recent Advances in Silver-Mediated Organic Synthesis Reactions".PROGRESS IN CHEMISTRY 23.6(2011):1137-1147. |
入库方式： OAI收割
来源：上海药物研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。