Rhodium-catalyzed Asymmetric Arylation of Nitroalkenes Powered by Simple Chiral Sulfur-Olefin Ligands
文献类型：期刊论文
| 作者 | Wang, Zheng; Chen, Wen-Wen ; Xu, Ming-Hua
|
| 刊名 | JOURNAL OF THE CHINESE CHEMICAL SOCIETY
 |
| 出版日期 | 2018-03 |
| 卷号 | 65期号:3页码:331-336 |
| 关键词 | Asymmetric catalysis Rhodium Chiral sulfur-olefin ligands Asymmetric arylation Nitroalkenes |
| ISSN号 | 0009-4536 |
| DOI | 10.1002/jccs.201700328 |
| 文献子类 | Article; Proceedings Paper |
| 英文摘要 | An efficient rhodium-catalyzed enantioselective addition of potassium organotrifluoroborates to nitroalkenes powered by simple chiral sulfur-olefin ligands is reported. This protocol is applicable to a broad range of 2-aryl-, alkyl-, and heteroaryl-substituted nitroalkenes, allowing access to diverse chiral beta, beta-disubstituted nitroethanes in good to excellent yields with high enantioselectivity under mild conditions. |
| WOS关键词 | HIGHLY ENANTIOSELECTIVE ARYLATION ; ELECTRON-DEFICIENT OLEFINS ; ARYLBORONIC ACIDS ; CONJUGATE ADDITION ; ORGANOBORONIC ACIDS ; EFFICIENT ACCESS ; BORONIC ACIDS ; PHOSPHITE-OLEFIN ; DIENE LIGANDS ; 1,4-ADDITION |
| 资助项目 | National Natural Science Foundation of China[21325209] ; National Natural Science Foundation of China[21472205] ; Shanghai Municipal Committee of Science and Technology (Program of Shanghai Academic Research Leader)[14XD1404400] |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000428444900006 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| 源URL | [http://119.78.100.183/handle/2S10ELR8/279863]  |
| 专题 | 药物化学研究室 中科院受体结构与功能重点实验室 新药研究国家重点实验室 |
| 通讯作者 | Xu, Ming-Hua |
| 作者单位 | Chinese Acad Sci, Shanghai Inst Mat Med, State Key Lab Drug Res, Shanghai 201203, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wang, Zheng,Chen, Wen-Wen,Xu, Ming-Hua. Rhodium-catalyzed Asymmetric Arylation of Nitroalkenes Powered by Simple Chiral Sulfur-Olefin Ligands[J]. JOURNAL OF THE CHINESE CHEMICAL SOCIETY,2018,65(3):331-336. |
| APA | Wang, Zheng,Chen, Wen-Wen,&Xu, Ming-Hua.(2018).Rhodium-catalyzed Asymmetric Arylation of Nitroalkenes Powered by Simple Chiral Sulfur-Olefin Ligands.JOURNAL OF THE CHINESE CHEMICAL SOCIETY,65(3),331-336. |
| MLA | Wang, Zheng,et al."Rhodium-catalyzed Asymmetric Arylation of Nitroalkenes Powered by Simple Chiral Sulfur-Olefin Ligands".JOURNAL OF THE CHINESE CHEMICAL SOCIETY 65.3(2018):331-336. |
入库方式： OAI收割
来源：上海药物研究所
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