Pd-Catalyzed Acetoxylation of gamma-C(sp(3))-H Bonds of Amines Directed by a Removable Bts-Protecting Group
文献类型：期刊论文
| 作者 | Zheng, Yong; Song, Weibin; Zhu, Yefu; Wei, Bole; Xuan, Lijiang
|
| 刊名 | JOURNAL OF ORGANIC CHEMISTRY
 |
| 出版日期 | 2018-02-16 |
| 卷号 | 83期号:4页码:2448-2454 |
| ISSN号 | 0022-3263 |
| DOI | 10.1021/acs.joc.7b02995 |
| 文献子类 | Article |
| 英文摘要 | Pd-catalyzed acetoxylation of gamma-C(sp(3))-H bonds directed by Bts-protected amines using inexpensive PhI(OAc)(2) as oxidant is reported. The Bts-protecting group is easily introduced and removed under mild conditions. This protocol provides an important strategy for the construction of gamma-hydroxyl amine derivatives. |
| WOS关键词 | C-H ACTIVATION ; NATIVE CHEMICAL LIGATION ; CARBON-HYDROGEN BONDS ; EFFICIENT SYNTHESES ; ACID-DERIVATIVES ; FUNCTIONALIZATION ; C(SP(3))-H ; C(SP(2))-H ; INHIBITOR ; AUXILIARY |
| 资助项目 | National Natural Science Foundation of China[81602995] |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000427094200081 |
| 出版者 | AMER CHEMICAL SOC |
| 源URL | [http://119.78.100.183/handle/2S10ELR8/279897]  |
| 专题 | 上海中药现代化研究中心 中科院受体结构与功能重点实验室 新药研究国家重点实验室 |
| 通讯作者 | Xuan, Lijiang |
| 作者单位 | Chinese Acad Sci, Shanghai Inst Mat Med, State Key Lab Drug Res, 501 Haike Rd, Shanghai 201203, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zheng, Yong,Song, Weibin,Zhu, Yefu,et al. Pd-Catalyzed Acetoxylation of gamma-C(sp(3))-H Bonds of Amines Directed by a Removable Bts-Protecting Group[J]. JOURNAL OF ORGANIC CHEMISTRY,2018,83(4):2448-2454. |
| APA | Zheng, Yong,Song, Weibin,Zhu, Yefu,Wei, Bole,&Xuan, Lijiang.(2018).Pd-Catalyzed Acetoxylation of gamma-C(sp(3))-H Bonds of Amines Directed by a Removable Bts-Protecting Group.JOURNAL OF ORGANIC CHEMISTRY,83(4),2448-2454. |
| MLA | Zheng, Yong,et al."Pd-Catalyzed Acetoxylation of gamma-C(sp(3))-H Bonds of Amines Directed by a Removable Bts-Protecting Group".JOURNAL OF ORGANIC CHEMISTRY 83.4(2018):2448-2454. |
入库方式： OAI收割
来源：上海药物研究所
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