中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Determination of absolute configuration using heavy atom based co-crystallization method: Halogen atom effects

文献类型:期刊论文

作者Wang, Jian-Rong2; Fan, Xiaowu1,2; Ding, Qiaoce2; Mei, Xuefeng2
刊名JOURNAL OF MOLECULAR STRUCTURE
出版日期2016-09-05
卷号1119页码:269-275
关键词Absolute configuration Co-crystallization Heavy atom Cholestanol L-Ascorbic acid Single-crystal X-ray diffraction
ISSN号0022-2860
DOI10.1016/j.molstruc.2016.04.084
文献子类Article
英文摘要Heavy atom (chloride, bromide, and iodide) based co-crystals for determination of absolute configuration (AC) for chiral molecules were synthesized and evaluated. Co-crystals of cholestanol and L-ascorbic acid were analysed and the effects and potential benefits of varying the heavy atom are discussed. Changing the halogen atoms (chloride, bromide, or iodide) affects the co-crystal formation, X-ray absorption, and anomalous dispersion, and hence the ability to determine AC. (C) 2016 Elsevier B.V. All rights reserved.
WOS关键词ORGANIC-SYNTHESIS ; CO-CRYSTAL ; CRYSTALLOGRAPHY
资助项目National Natural Science Foundation of China[81273479] ; National Natural Science Foundation of China[81402898] ; CAS Key Technology Talent Program[00000000] ; Youth Innovation Promotion Association CAS[2016257]
WOS研究方向Chemistry
语种英语
WOS记录号WOS:000378360000032
出版者ELSEVIER SCIENCE BV
源URL[http://119.78.100.183/handle/2S10ELR8/275900]  
专题药物质量控制与固体化学研究中心
通讯作者Mei, Xuefeng
作者单位1.Univ Sci & Technol China, Nano Sci & Technol Inst, Suzhou 215123, Jiangsu, Peoples R China
2.Chinese Acad Sci, Shanghai Inst Mat Med, Pharmaceut Analyt & Solid State Chem Res Ctr, Shanghai 201203, Peoples R China;
推荐引用方式
GB/T 7714
Wang, Jian-Rong,Fan, Xiaowu,Ding, Qiaoce,et al. Determination of absolute configuration using heavy atom based co-crystallization method: Halogen atom effects[J]. JOURNAL OF MOLECULAR STRUCTURE,2016,1119:269-275.
APA Wang, Jian-Rong,Fan, Xiaowu,Ding, Qiaoce,&Mei, Xuefeng.(2016).Determination of absolute configuration using heavy atom based co-crystallization method: Halogen atom effects.JOURNAL OF MOLECULAR STRUCTURE,1119,269-275.
MLA Wang, Jian-Rong,et al."Determination of absolute configuration using heavy atom based co-crystallization method: Halogen atom effects".JOURNAL OF MOLECULAR STRUCTURE 1119(2016):269-275.

入库方式: OAI收割

来源:上海药物研究所

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