A pair of unprecedented cyclohexylethanoid enantiomers containing unusual trioxabicyclo[4.2.1]nonane ring from Clerodendrum bungei
文献类型：期刊论文
| 作者 | Zhu, Hucheng1; Huan, Lijun4; Chen, Chunmei1; Yang, Jing3; He, Jiangbo2; Chen, Yong4; Yao, Guangmin1; Luo, Zengwei1; Xue, Yongbo1; Zhang, Yonghui1 |
| 刊名 | TETRAHEDRON LETTERS
 |
| 出版日期 | 2014-04-02 |
| 卷号 | 55期号:14页码:2277-2279 |
| 关键词 | Clerodendrum bungei Enantiomer X-ray ECD |
| ISSN号 | 0040-4039 |
| DOI | 10.1016/j.tetlet.2014.02.088 |
| 文献子类 | Article |
| 英文摘要 | A pair of unprecedented enantiomers (1a/1b) of cyclohexylethanoid bearing an unusual trioxabicyclo[4.2.1]nonane ring, along with two known structurally related cyclohexylethanoids, (+)-rengyolone (2) and cleroindicin E (3), were isolated from the aerial parts of Clerodendrum bungei. The structures and absolute configurations of the enantiomers were determined by comprehensive spectroscopic analysis, single-crystal X-ray diffraction, and quantum mechanical calculation of the electronic circular dichroic (ECD) spectra. The postulated biogenetic pathway of 1a/1b was also discussed. (C) 2014 Elsevier Ltd. All rights reserved. |
| WOS关键词 | GLYCOLALDEHYDE ; DITERPENOIDS ; CONSTITUENTS |
| 资助项目 | Program for New Century Excellent Talents in University, State Education Ministry of China[NCET-2008-0224] |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000334817900026 |
| 出版者 | PERGAMON-ELSEVIER SCIENCE LTD |
| 源URL | [http://119.78.100.183/handle/2S10ELR8/277121]  |
| 专题 | 药物发现与设计中心 |
| 通讯作者 | Xue, Yongbo |
| 作者单位 | 1.Huazhong Univ Sci & Technol, Tongi Med Coll, Sch Pharm, Hubei Key Lab Nat Med Chem & Resource Evaluat, Wuhan 430030, Peoples R China; 2.Chinese Acad Sci, Kunming Inst Bot, State Key Lab Phytochem & Plant Resources West Ch, Kunming 650204, Peoples R China 3.Chinese Acad Sci, Shanghai Inst Mat Med, Shanghai 201203, Peoples R China; 4.Hubei Univ, Coll Life Sci, Wuhan 430062, Peoples R China; |
| 推荐引用方式 GB/T 7714 | Zhu, Hucheng,Huan, Lijun,Chen, Chunmei,et al. A pair of unprecedented cyclohexylethanoid enantiomers containing unusual trioxabicyclo[4.2.1]nonane ring from Clerodendrum bungei[J]. TETRAHEDRON LETTERS,2014,55(14):2277-2279. |
| APA | Zhu, Hucheng.,Huan, Lijun.,Chen, Chunmei.,Yang, Jing.,He, Jiangbo.,...&Zhang, Yonghui.(2014).A pair of unprecedented cyclohexylethanoid enantiomers containing unusual trioxabicyclo[4.2.1]nonane ring from Clerodendrum bungei.TETRAHEDRON LETTERS,55(14),2277-2279. |
| MLA | Zhu, Hucheng,et al."A pair of unprecedented cyclohexylethanoid enantiomers containing unusual trioxabicyclo[4.2.1]nonane ring from Clerodendrum bungei".TETRAHEDRON LETTERS 55.14(2014):2277-2279. |
入库方式： OAI收割
来源：上海药物研究所
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