A Direct Amine-Palladium Acetate Cocatalyzed Saegusa Oxidation Reaction of Unmodified Aldehydes to alpha,beta-Unsaturated Aldehydes
文献类型：期刊论文
| 作者 | Zhu, Jin2; Liu, Jie2; Ma, Ruoqun2; Xie, Hexin1; Li, Jian2; Jiang, Hualiang2,3 ; Wang, Wei2,3
|
| 刊名 | ADVANCED SYNTHESIS & CATALYSIS
 |
| 出版日期 | 2009-06 |
| 卷号 | 351期号:9页码:1229-1232 |
| 关键词 | aminocatalysis organocatalysis Saegusa reaction alpha,beta-unsaturated aldehydes |
| ISSN号 | 1615-4150 |
| DOI | 10.1002/adsc.200900011 |
| 文献子类 | Article |
| 英文摘要 | A direct preparation of synthetically useful alpha,beta-unsaturated aldehydes from readily available aldehydes has been developed. The process is effectively cocatalyzed by an amine-palladium acetate to give rise to alpha,beta-unsaturated aldehydes in moderate to good yields (41-62%). The reaction features the use of unmodified aldehydes rather than enol silyl ethers, which are used in a typical Saegusa oxidation reaction. |
| WOS关键词 | CARBONYL-COMPOUNDS ; SYNTHETIC ASPECTS ; ADDITIONS ; MECHANISM |
| 资助项目 | National Natural Science Foundation of China[90813005] ; 863 Hi-Tech Program of China[2006AA020404] ; China III Project[807023] ; Shanghai Rising-Star Program (A type) of Shanghai Ministry of Science and Technology[07A14013] |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000267894000005 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| 源URL | [http://119.78.100.183/handle/2S10ELR8/279219]  |
| 专题 | 药物发现与设计中心 药理学第二研究室 |
| 通讯作者 | Li, Jian |
| 作者单位 | 1.Univ New Mexico, Dept Chem & Biol Chem, Albuquerque, NM 87131 USA; 2.E China Univ Sci & Technol, Sch Pharm, Shanghai 200237, Peoples R China; 3.Chinese Acad Sci, Shanghai Inst Mat Med, Drug Discovery & Design Ctr, Shanghai 201203, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhu, Jin,Liu, Jie,Ma, Ruoqun,et al. A Direct Amine-Palladium Acetate Cocatalyzed Saegusa Oxidation Reaction of Unmodified Aldehydes to alpha,beta-Unsaturated Aldehydes[J]. ADVANCED SYNTHESIS & CATALYSIS,2009,351(9):1229-1232. |
| APA | Zhu, Jin.,Liu, Jie.,Ma, Ruoqun.,Xie, Hexin.,Li, Jian.,...&Wang, Wei.(2009).A Direct Amine-Palladium Acetate Cocatalyzed Saegusa Oxidation Reaction of Unmodified Aldehydes to alpha,beta-Unsaturated Aldehydes.ADVANCED SYNTHESIS & CATALYSIS,351(9),1229-1232. |
| MLA | Zhu, Jin,et al."A Direct Amine-Palladium Acetate Cocatalyzed Saegusa Oxidation Reaction of Unmodified Aldehydes to alpha,beta-Unsaturated Aldehydes".ADVANCED SYNTHESIS & CATALYSIS 351.9(2009):1229-1232. |
入库方式： OAI收割
来源：上海药物研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。