Studies on the mass spectrometric behavior of four types of Stemona alkaloids
文献类型：期刊论文
| 作者 | Peng, SP; Sheng, JH; Ye, Y
|
| 刊名 | CHINESE JOURNAL OF ANALYTICAL CHEMISTRY
 |
| 出版日期 | 2006-04 |
| 卷号 | 34期号:4页码:497-502 |
| 关键词 | Stemona alkaloids electrospray ionization mass spectrometry mass spetrometry/mass spectrometrz fragmentation pathways |
| ISSN号 | 0253-3820 |
| DOI | 10.1016/S1872-2040(06)60027-3 |
| 文献子类 | Article |
| 英文摘要 | The mass spectrometric behavior of four types of Stemona alkaloids was studied. Electron impact (EI) mass spectra showed the molecular ion with moderate intensity and [M-99](+) ion as base peak. The other ions were relatively weak. EI spectra did not give much useful information for structural determination. However, electrospray ionization (ESI) and atmosphere pressure chemical ionization (APCI) mass spectra showed the pseudo molecular ions [M+H](+) of four compounds as base peak. The characteristic ions [M-100](+) and [M-74](+) corresponding to the alpha-methyl-gamma-butyrolactone ring were also observed. The results showed MS2 spectra of soft ionization could provide more structural information. The fragmentation pathways of four compounds were deduced. The mass spectrometric behavior reflected their structural similarities and differences. Soft ionization technique is the best choice for the structural identification of Stemona alkaloid. It will provide an important tool in the structural identification of this kind of compounds. |
| WOS研究方向 | Chemistry |
| 语种 | 中文 |
| CSCD记录号 | CSCD:2471766 |
| WOS记录号 | WOS:000237325400014 |
| 出版者 | SCIENCE PRESS |
| 源URL | [http://119.78.100.183/handle/2S10ELR8/273624]  |
| 专题 | 天然药物化学研究室 |
| 通讯作者 | Ye, Y |
| 作者单位 | Chinese Acad Sci, Shanghai Inst Mat Med, Shanghai 201203, Peoples R China |
| 推荐引用方式 GB/T 7714 | Peng, SP,Sheng, JH,Ye, Y. Studies on the mass spectrometric behavior of four types of Stemona alkaloids[J]. CHINESE JOURNAL OF ANALYTICAL CHEMISTRY,2006,34(4):497-502. |
| APA | Peng, SP,Sheng, JH,&Ye, Y.(2006).Studies on the mass spectrometric behavior of four types of Stemona alkaloids.CHINESE JOURNAL OF ANALYTICAL CHEMISTRY,34(4),497-502. |
| MLA | Peng, SP,et al."Studies on the mass spectrometric behavior of four types of Stemona alkaloids".CHINESE JOURNAL OF ANALYTICAL CHEMISTRY 34.4(2006):497-502. |
入库方式： OAI收割
来源：上海药物研究所
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