Direct Oxidation of beta-Aryl Substituted Aldehydes to alpha,beta-Unsaturated Aldehydes Promoted by an o-Anisidine-Pd(OAc)(2) Co-catalyst
文献类型:期刊论文
作者 | Liu, Jie2; Zhu, Jin2; Jiang, Hualiang1,2![]() |
刊名 | CHEMISTRY-AN ASIAN JOURNAL
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出版日期 | 2009 |
卷号 | 4期号:11页码:1712-1716 |
关键词 | aldehydes anisidine organocatalysis palladium Saegusa reaction |
ISSN号 | 1861-4728 |
DOI | 10.1002/asia.200900238 |
文献子类 | Article |
英文摘要 | An o-anisidine-Pd(OAc)(2) catalytic system for the direct co-catalytic Saegusa oxidation of beta-aryl substituted aldehydes to alpha,beta-unsaturated aldehydes has been developed. The use of o-anisidine in place of (S)-diphenylprolinol made the process more simply and cost-effective. The process not only features the use of unmodified aldehydes rather than enol silyl ethers, but also gives moderate to good yields (44-72%) |
WOS关键词 | ACROLEIN DIETHYL ACETAL ; SYNTHETIC ASPECTS ; ADDITIONS ; CINNAMALDEHYDES |
资助项目 | National Natural Science Foundation of China[90813005] ; 863 Hi-Tech Program of China[2006AA020404] ; China 111 Project[B07023] ; Shanghai Ministry of Science and Technology[07A14013] |
WOS研究方向 | Chemistry |
语种 | 英语 |
WOS记录号 | WOS:000271814800010 |
出版者 | WILEY-V C H VERLAG GMBH |
源URL | [http://119.78.100.183/handle/2S10ELR8/279356] ![]() |
专题 | 药理学第二研究室 |
通讯作者 | Wang, Wei |
作者单位 | 1.Chinese Acad Sci, Shanghai Inst Mat Med, Drug Discovery & Design Ctr, Shanghai 201203, Peoples R China 2.E China Univ Sci & Technol, Sch Pharm, Shanghai 200237, Peoples R China; 3.Univ New Mexico, Dept Chem & Chem Biol, Albuquerque, NM 87131 USA; |
推荐引用方式 GB/T 7714 | Liu, Jie,Zhu, Jin,Jiang, Hualiang,et al. Direct Oxidation of beta-Aryl Substituted Aldehydes to alpha,beta-Unsaturated Aldehydes Promoted by an o-Anisidine-Pd(OAc)(2) Co-catalyst[J]. CHEMISTRY-AN ASIAN JOURNAL,2009,4(11):1712-1716. |
APA | Liu, Jie,Zhu, Jin,Jiang, Hualiang,Wang, Wei,&Li, Jian.(2009).Direct Oxidation of beta-Aryl Substituted Aldehydes to alpha,beta-Unsaturated Aldehydes Promoted by an o-Anisidine-Pd(OAc)(2) Co-catalyst.CHEMISTRY-AN ASIAN JOURNAL,4(11),1712-1716. |
MLA | Liu, Jie,et al."Direct Oxidation of beta-Aryl Substituted Aldehydes to alpha,beta-Unsaturated Aldehydes Promoted by an o-Anisidine-Pd(OAc)(2) Co-catalyst".CHEMISTRY-AN ASIAN JOURNAL 4.11(2009):1712-1716. |
入库方式: OAI收割
来源:上海药物研究所
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