Progress of Organic Reactions Catalyzed by N-Heterocyclic Carbenes
文献类型：期刊论文
| 作者 | Wang Ao1,2,3; Xiao Yonglong1; Zhou Yu1 ; Xu Jinyi2,3; Liu Hong1
|
| 刊名 | CHINESE JOURNAL OF ORGANIC CHEMISTRY
 |
| 出版日期 | 2017-10-25 |
| 卷号 | 37期号:10页码:2590-2608 |
| 关键词 | N-heterocyclic carbene organic catalytic umpolung |
| ISSN号 | 0253-2786 |
| DOI | 10.6023/cjoc201702041 |
| 文献子类 | Review |
| 英文摘要 | Since the first stable N-heterocyclic carbene was isolated by Arduengo in 1991, N-heterocyclic carbine has developed rapidly as a kind of efficient organic catalyst. It plays important role in building complex molecules in organic synthesis for the characteristics of umpolung. Some special Lewis bases and oxidants can induce carbine reaction with carbonyl to form Breslow intermediates, enol and homoenolate, which expand the reaction greatly. In this paper, the recent progresses in organic catalytic reactions including Stetter reaction, a(3)-d(3) umpolung catalyzed by carbines are reviewed. |
| WOS关键词 | ACID COOPERATIVE CATALYSIS ; DYNAMIC KINETIC RESOLUTION ; ISATIN-DERIVED KETIMINES ; HIGHLY ENANTIOSELECTIVE ROUTE ; DIELS-ALDER REACTIONS ; AZA-BENZOIN REACTION ; STETTER REACTION ; ASYMMETRIC-SYNTHESIS ; ALIPHATIC-ALDEHYDES ; GAMMA-LACTAMS |
| 资助项目 | National Natural Science Foundation of China[21632008] |
| WOS研究方向 | Chemistry |
| 语种 | 中文 |
| CSCD记录号 | CSCD:6109436 |
| WOS记录号 | WOS:000416643900009 |
| 出版者 | SCIENCE PRESS |
| 源URL | [http://119.78.100.183/handle/2S10ELR8/272439]  |
| 专题 | 药物化学研究室 药理学第一研究室 |
| 通讯作者 | Zhou Yu; Liu Hong |
| 作者单位 | 1.Chinese Acad Sci, Shanghai Inst Mat Med, CAS Key Lab Receptor Res, Shanghai 201203, Peoples R China 2.China Pharmaceut Univ, State Key Lab Nat Med, Nanjing 210000, Jiangsu, Peoples R China; 3.China Pharmaceut Univ, Dept Med Chem, Nanjing 210000, Jiangsu, Peoples R China; |
| 推荐引用方式 GB/T 7714 | Wang Ao,Xiao Yonglong,Zhou Yu,et al. Progress of Organic Reactions Catalyzed by N-Heterocyclic Carbenes[J]. CHINESE JOURNAL OF ORGANIC CHEMISTRY,2017,37(10):2590-2608. |
| APA | Wang Ao,Xiao Yonglong,Zhou Yu,Xu Jinyi,&Liu Hong.(2017).Progress of Organic Reactions Catalyzed by N-Heterocyclic Carbenes.CHINESE JOURNAL OF ORGANIC CHEMISTRY,37(10),2590-2608. |
| MLA | Wang Ao,et al."Progress of Organic Reactions Catalyzed by N-Heterocyclic Carbenes".CHINESE JOURNAL OF ORGANIC CHEMISTRY 37.10(2017):2590-2608. |
入库方式： OAI收割
来源：上海药物研究所
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