Analysis of crystallographic structures of Ni(II) complexes of a-amino acid Schiff bases: elucidation of the substituent effect on stereochemical preferences
文献类型：期刊论文
| 作者 | Nian, Yong1,5; Wang, Jiang1,5 ; Moriwaki, Hiroki2; Soloshonok, Vadim A.3,4; Liu, Hong1,5
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| 刊名 | DALTON TRANSACTIONS
 |
| 出版日期 | 2017-04-07 |
| 卷号 | 46期号:13页码:4191-4198 |
| ISSN号 | 1477-9226 |
| DOI | 10.1039/c7dt00014f |
| 文献子类 | Article |
| 英文摘要 | In this study, we performed critical analysis of 13 crystallographic structures of various Ni(II) complexes of amino acid Schiff bases. The major finding of this work is the significance of a parallel displaced type of aromatic interactions between o-amino-benzophenone and Pro N-benzyl rings. The quality of these aromatic interactions was shown to control the steric environment around the amino acid side-chain, rendering variously substituted Ni(II) complexes of different thermodynamic stabilities. The discovered structural trend holds true for aliphatic, aromatic and sterically bulky amino acids and can be used for the rational design of new and more efficient chiral ligands for general asymmetric synthesis of tailor-made a-amino acids. |
| WOS关键词 | EFFICIENT ASYMMETRIC-SYNTHESIS ; NUCLEOPHILIC GLYCINE EQUIVALENTS ; DYNAMIC KINETIC RESOLUTION ; FACE AROMATIC INTERACTIONS ; PI-PI INTERACTIONS ; OPERATIONALLY CONVENIENT CONDITIONS ; PURE 4-AMINOGLUTAMIC ACIDS ; MICHAEL ADDITION-REACTIONS ; NI-II COMPLEXES ; ALPHA-AMINO |
| 资助项目 | National Natural Science Foundation of China[21632008] ; National Natural Science Foundation of China[81620108207] ; National Natural Science Foundation of China[9122904] ; Major Project of Chinese National Programs for Fundamental Research and Development[2015CB910304] ; National S&T Major Projects[2014ZX09507002-001] ; Ikerbasque[00000000] ; Basque Foundation for Science[00000000] |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000397884100010 |
| 出版者 | ROYAL SOC CHEMISTRY |
| 源URL | [http://119.78.100.183/handle/2S10ELR8/272706]  |
| 专题 | 药物化学研究室 |
| 通讯作者 | Soloshonok, Vadim A.; Liu, Hong |
| 作者单位 | 1.Univ Chinese Acad Sci, 19A Yuquan Rd, Beijing 100049, Peoples R China; 2.Hamari Chem Ltd, Higashi Ku, Yodogawa Ku, 1-4-29 Kunijima, Osaka 5330024, Japan; 3.Univ Basque Country UPV EHU, Fac Chem, Dept Organ Chem 1, Paseo Manuel Lardizabal 3, San Sebastian 20018, Spain; 4.Ikerbasque, Basque Fdn Sci, Maria Diaz de Haro 3, Bilbao 48013, Spain 5.Chinese Acad Sci, Shanghai Inst Mat Med, CAS Key Lab Receptor Res, 555 Zuchongzhi Rd, Shanghai 201203, Peoples R China; |
| 推荐引用方式 GB/T 7714 | Nian, Yong,Wang, Jiang,Moriwaki, Hiroki,et al. Analysis of crystallographic structures of Ni(II) complexes of a-amino acid Schiff bases: elucidation of the substituent effect on stereochemical preferences[J]. DALTON TRANSACTIONS,2017,46(13):4191-4198. |
| APA | Nian, Yong,Wang, Jiang,Moriwaki, Hiroki,Soloshonok, Vadim A.,&Liu, Hong.(2017).Analysis of crystallographic structures of Ni(II) complexes of a-amino acid Schiff bases: elucidation of the substituent effect on stereochemical preferences.DALTON TRANSACTIONS,46(13),4191-4198. |
| MLA | Nian, Yong,et al."Analysis of crystallographic structures of Ni(II) complexes of a-amino acid Schiff bases: elucidation of the substituent effect on stereochemical preferences".DALTON TRANSACTIONS 46.13(2017):4191-4198. |
入库方式： OAI收割
来源：上海药物研究所
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