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Study on mass spectrometric behavior of samarium di-iodide in tetrahydrofuran solution

文献类型：期刊论文

作者Zhou, Jing2; Feng, Chen-Guo2; Xu, Ming-Hua1; Lin, Guo-Qiang2; Guo, Yinlong2
刊名INTERNATIONAL JOURNAL OF MASS SPECTROMETRY
出版日期2008-02-15
卷号270期号:1-2页码:62-67
关键词samarium complex mass spectrometry
ISSN号1387-3806
DOI10.1016/j.ijms.2007.12.001
文献子类Article
英文摘要The mass spectrometric behavior of the SmI2 in tetrahydrofuran (THF) solution was studied by ESI-Q-MS/MS and ESI-TOF-MS. Results obtained show that the trivalent samarium ions were the dominating species observed, which could be explained by the electron donor nature of the Sm-II. The rich coordination chemistry around Sm-II and Sm-III centers were also discussed. Besides, the fast ligand exchange of the THF-solvated samarium complexes with hexamethylphosphoramide (HMPA) was monitored by on-line ESI-Q-MS, which demonstrated the strong coordination of HMPA to samarium. (c) 2007 Elsevier B.V. All rights reserved.
WOS关键词ORGANOMETALLIC CHEMISTRY ; ELECTROSPRAY-IONIZATION ; ORGANIC-SYNTHESIS ; REDUCING POWER ; GAS-PHASE ; SMI2 ; COMPLEXES ; COSOLVENT ; REAGENTS ; THF/HMPA
WOS研究方向Physics ; Spectroscopy
语种英语
WOS记录号WOS:000253115800009
出版者ELSEVIER SCIENCE BV
源URL[http://119.78.100.183/handle/2S10ELR8/272979]  
专题药物化学研究室
通讯作者Guo, Yinlong
作者单位1.Chinese Acad Sci, Shanghai Inst Mat Med, Shanghai 201203, Peoples R China
2.Chinese Acad Sci, Shanghai Mass Spectrometry Ctr, Shanghai Inst Organ Chem, Shanghai 200032, Peoples R China;
推荐引用方式
GB/T 7714		 Zhou, Jing,Feng, Chen-Guo,Xu, Ming-Hua,et al. Study on mass spectrometric behavior of samarium di-iodide in tetrahydrofuran solution[J]. INTERNATIONAL JOURNAL OF MASS SPECTROMETRY,2008,270(1-2):62-67.
APA Zhou, Jing,Feng, Chen-Guo,Xu, Ming-Hua,Lin, Guo-Qiang,&Guo, Yinlong.(2008).Study on mass spectrometric behavior of samarium di-iodide in tetrahydrofuran solution.INTERNATIONAL JOURNAL OF MASS SPECTROMETRY,270(1-2),62-67.
MLA Zhou, Jing,et al."Study on mass spectrometric behavior of samarium di-iodide in tetrahydrofuran solution".INTERNATIONAL JOURNAL OF MASS SPECTROMETRY 270.1-2(2008):62-67.

入库方式： OAI收割

来源：上海药物研究所

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