Synthesis and determination of absolute configuration of tetracetate 4a-carba-D-xylofuranoside
文献类型：期刊论文
| 作者 | Xue, ZJ; Chen, P; Peng, SY; Li, YC |
| 刊名 | TETRAHEDRON
 |
| 出版日期 | 2006-01-02 |
| 卷号 | 62期号:1页码:199-204 |
| 关键词 | tetracetate 4a-carba-D-xylofuranoside ring-closing enyne metathesis stereoselective hydrogenation absolute configuration |
| ISSN号 | 0040-4020 |
| DOI | 10.1016/j.tet.2005.09.139 |
| 文献子类 | Article |
| 英文摘要 | The synthesis of carbasugar analogue tetracetate 4a-carba-D-xylofuranoside (1) was reported. The new route involved the conversion of D-(-)-tartatic acid into an enyne compound, which was then cyclized via a key ring-closing enyne metathesis to form the key intermediate 1-vinyl cyclopentene 9, which was then stereoselectively converted to our target. The absolute configuration of the en ne was determined by modified Mosher's method, while that of tetracetate 4a-carba-D-xylofuranoside by ROSEY spectroscopy and gamma-gauche effect. (c) 2005 Elsevier Ltd. All rights reserved. |
| WOS关键词 | ENYNE METATHESIS ; METHYL 4A-CARBA-D-ARABINOFURANOSIDES ; STEREOSELECTIVE-SYNTHESIS ; INHIBITORS ; SELECTIVITY |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000234093500022 |
| 出版者 | PERGAMON-ELSEVIER SCIENCE LTD |
| 源URL | [http://119.78.100.183/handle/2S10ELR8/273690]  |
| 专题 | 药物化学研究室 |
| 通讯作者 | Li, YC |
| 作者单位 | Chinese Acad Sci, Shanghai Inst Mat Med, Shanghai 201203, Peoples R China |
| 推荐引用方式 GB/T 7714 | Xue, ZJ,Chen, P,Peng, SY,et al. Synthesis and determination of absolute configuration of tetracetate 4a-carba-D-xylofuranoside[J]. TETRAHEDRON,2006,62(1):199-204. |
| APA | Xue, ZJ,Chen, P,Peng, SY,&Li, YC.(2006).Synthesis and determination of absolute configuration of tetracetate 4a-carba-D-xylofuranoside.TETRAHEDRON,62(1),199-204. |
| MLA | Xue, ZJ,et al."Synthesis and determination of absolute configuration of tetracetate 4a-carba-D-xylofuranoside".TETRAHEDRON 62.1(2006):199-204. |
入库方式： OAI收割
来源：上海药物研究所
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