Cobalt-Catalyzed Carbonylation of C(sp(2))-H Bonds with Azodicarboxylate as the Carbonyl Source
文献类型：期刊论文
| 作者 | Ni, Jiabin1,2,3; Li, Jie1,2,4; Fan, Zhoulong1,2,3; Zhang, Ao1,2,3,4
|
| 刊名 | ORGANIC LETTERS
 |
| 出版日期 | 2016-11-18 |
| 卷号 | 18期号:22页码:5960-5963 |
| ISSN号 | 1523-7060 |
| DOI | 10.1021/acs.orglett.6b03111 |
| 文献子类 | Article |
| 英文摘要 | A novel and efficient approach for the C(sp(2))-H bond carbonylation of benzamides has been developed using stable and inexpensive Co(OAc)(2).4H(2)O as the catalyst and the commercially available and easily handling azodicarboxylates as the nontoxic carbonyl source. A broad range of substrates bearing diverse functional groups were tolerated. This is the first example where cobalt-catalyzed C(sp(2))-H bond carbonylation occurs with azodicarboxylate as the carbonyl source. |
| WOS关键词 | C-H BOND ; DIETHYL AZODICARBOXYLATE ; ROOM-TEMPERATURE ; TERMINAL ALKYNES ; ACTIVATION ; AMIDES ; FUNCTIONALIZATION ; ANNULATION ; AMINATION ; ACCESS |
| 资助项目 | Chinese NSF[81430080] ; Chinese NSF[81373277] ; Major State Basic Research Development Program[2015CB910603] ; Program of Shanghai Subject Chief Scientist[16XD1404600] |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000388428600048 |
| 出版者 | AMER CHEMICAL SOC |
| 源URL | [http://119.78.100.183/handle/2S10ELR8/275805]  |
| 专题 | 药物化学研究室 |
| 通讯作者 | Zhang, Ao |
| 作者单位 | 1.Chinese Acad Sci, Shanghai Inst Mat Med, CAS Key Lab Receptor Res, Shanghai 201203, Peoples R China; 2.Chinese Acad Sci, Shanghai Inst Mat Med, Synthet Organ & Med Chem Lab, Shanghai 201203, Peoples R China; 3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China; 4.ShanghaiTech Univ, Shanghai 20120, Peoples R China |
| 推荐引用方式 GB/T 7714 | Ni, Jiabin,Li, Jie,Fan, Zhoulong,et al. Cobalt-Catalyzed Carbonylation of C(sp(2))-H Bonds with Azodicarboxylate as the Carbonyl Source[J]. ORGANIC LETTERS,2016,18(22):5960-5963. |
| APA | Ni, Jiabin,Li, Jie,Fan, Zhoulong,&Zhang, Ao.(2016).Cobalt-Catalyzed Carbonylation of C(sp(2))-H Bonds with Azodicarboxylate as the Carbonyl Source.ORGANIC LETTERS,18(22),5960-5963. |
| MLA | Ni, Jiabin,et al."Cobalt-Catalyzed Carbonylation of C(sp(2))-H Bonds with Azodicarboxylate as the Carbonyl Source".ORGANIC LETTERS 18.22(2016):5960-5963. |
入库方式： OAI收割
来源：上海药物研究所
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