Rhodium(III)-catalyzed alkyllation of primary C(sp(3))-H bonds with alpha-diazocarbonyl compounds
文献类型：期刊论文
| 作者 | Hou, Wei1,2; Yang, Yaxi1,2 ; Wu, Yunxiang1,2; Feng, Huijin1,2; Li, Yuanchao1,2; Zhou, Bing1,2
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| 刊名 | CHEMICAL COMMUNICATIONS
 |
| 出版日期 | 2016-08-11 |
| 卷号 | 52期号:62页码:9672-9675 |
| ISSN号 | 1359-7345 |
| DOI | 10.1039/c6cc03846h |
| 文献子类 | Article |
| 英文摘要 | Rh(III)-catalyzed intermolecular chelation-assisted insertion of carbenes derived from alpha-diazocarbonyl compounds into non-acidic primary sp(3) C-H bonds, for the first time, is reported under mild reaction conditions, thus affording a good complement to previous metal-carbenoid-induced primary C(sp(3))-H insertion reactions. We believe that this method will open up a new avenue for primary sp(3) C-H functionalization with alpha-diazocarbonyl compounds. |
| WOS关键词 | C-H ACTIVATION ; CARBON-HYDROGEN INSERTION ; INTERMOLECULAR CARBENOID FUNCTIONALIZATION ; DIAZO-COMPOUNDS ; RH(III)-CATALYZED SYNTHESIS ; N-PHENOXYACETAMIDES ; CATALYZED-REACTIONS ; ROOM-TEMPERATURE ; ARYLATION ; ALKYNES |
| 资助项目 | CAS[00000000] ; National Natural Science Foundation of China[21302200] |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000381328500013 |
| 出版者 | ROYAL SOC CHEMISTRY |
| 源URL | [http://119.78.100.183/handle/2S10ELR8/275927]  |
| 专题 | 药物化学研究室 |
| 通讯作者 | Zhou, Bing |
| 作者单位 | 1.Chinese Acad Sci, Shanghai Inst Mat Med, 555 Zu Chong Zhi Rd, Shanghai 201203, Peoples R China; 2.Univ Chinese Acad Sci, 19A Yuquan Rd, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Hou, Wei,Yang, Yaxi,Wu, Yunxiang,et al. Rhodium(III)-catalyzed alkyllation of primary C(sp(3))-H bonds with alpha-diazocarbonyl compounds[J]. CHEMICAL COMMUNICATIONS,2016,52(62):9672-9675. |
| APA | Hou, Wei,Yang, Yaxi,Wu, Yunxiang,Feng, Huijin,Li, Yuanchao,&Zhou, Bing.(2016).Rhodium(III)-catalyzed alkyllation of primary C(sp(3))-H bonds with alpha-diazocarbonyl compounds.CHEMICAL COMMUNICATIONS,52(62),9672-9675. |
| MLA | Hou, Wei,et al."Rhodium(III)-catalyzed alkyllation of primary C(sp(3))-H bonds with alpha-diazocarbonyl compounds".CHEMICAL COMMUNICATIONS 52.62(2016):9672-9675. |
入库方式： OAI收割
来源：上海药物研究所
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