Rh(III)- or Ir(III)-catalyzed ynone synthesis from aldehydes via chelation-assisted C-H bond activation
文献类型：期刊论文
| 作者 | Ai, Wen1,2; Wu, Yunxiang2; Tang, Huanyu2; Yang, Xueyan1; Yang, Yaxi2 ; Li, Yuanchao2; Zhou, Bing2
|
| 刊名 | CHEMICAL COMMUNICATIONS
 |
| 出版日期 | 2015 |
| 卷号 | 51期号:37页码:7871-7874 |
| ISSN号 | 1359-7345 |
| DOI | 10.1039/c5cc00758e |
| 文献子类 | Article |
| 英文摘要 | A Rh(III)- or Ir(III)-catalyzed direct aldehyde C-H alkynylation was developed for the first time as a simple and practical method for the synthesis of ynones. This catalytic reaction proceeds under mild reaction conditions and tolerates a variety of synthetically important functional groups (e.g., chloro, bromo, aldehyde), thus providing a good complement to previous methods. |
| WOS关键词 | 3-COMPONENT PYRIMIDINE SYNTHESIS ; N-SULFONYL 2-AMINOBENZALDEHYDES ; CATALYZED DIRECT ALKYNYLATION ; ROOM-TEMPERATURE ; EFFICIENT SYNTHESIS ; 2,5-DISUBSTITUTED FURANS ; ACETYLENIC KETONES ; TERMINAL ALKYNES ; RHODIUM COMPLEX ; ACID-CHLORIDES |
| 资助项目 | National Natural Science Foundation of China[21302200] |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000353639300023 |
| 出版者 | ROYAL SOC CHEMISTRY |
| 源URL | [http://119.78.100.183/handle/2S10ELR8/276734]  |
| 专题 | 药物化学研究室 |
| 通讯作者 | Yang, Yaxi |
| 作者单位 | 1.E China Univ Sci & Technol, Key Lab Adv Mat, Shanghai 200237, Peoples R China; 2.Chinese Acad Sci, Shanghai Inst Mat Med, Shanghai 201203, Peoples R China |
| 推荐引用方式 GB/T 7714 | Ai, Wen,Wu, Yunxiang,Tang, Huanyu,et al. Rh(III)- or Ir(III)-catalyzed ynone synthesis from aldehydes via chelation-assisted C-H bond activation[J]. CHEMICAL COMMUNICATIONS,2015,51(37):7871-7874. |
| APA | Ai, Wen.,Wu, Yunxiang.,Tang, Huanyu.,Yang, Xueyan.,Yang, Yaxi.,...&Zhou, Bing.(2015).Rh(III)- or Ir(III)-catalyzed ynone synthesis from aldehydes via chelation-assisted C-H bond activation.CHEMICAL COMMUNICATIONS,51(37),7871-7874. |
| MLA | Ai, Wen,et al."Rh(III)- or Ir(III)-catalyzed ynone synthesis from aldehydes via chelation-assisted C-H bond activation".CHEMICAL COMMUNICATIONS 51.37(2015):7871-7874. |
入库方式： OAI收割
来源：上海药物研究所
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