Rhodium- Catalyzed Direct Amination of Arenes with Nitrosobenzenes: A New Route to Diarylamines
文献类型：期刊论文
| 作者 | Du, Juanjuan; Yang, Yaxi ; Feng, Huijin; Li, Yuanchao; Zhou, Bing
|
| 刊名 | CHEMISTRY-A EUROPEAN JOURNAL
 |
| 出版日期 | 2014-05-05 |
| 卷号 | 20期号:19页码:5727-5731 |
| 关键词 | CH activation diarylamines isatin nitrosobenzenes rhodium |
| ISSN号 | 0947-6539 |
| DOI | 10.1002/chem.201400221 |
| 文献子类 | Article |
| 英文摘要 | A Rh-III-catalyzed addition of aryl CH bonds to nitrosobenzenes, followed by cleavage of the resulting hydroxylamines in situ, has been reported. Different directing groups, such as N-based heterocycles and ketoximes, can be used in this CH amination process, providing valuable diarylamines in excellent yields. Most importantly, this process provides a new method for attaching arylamine groups to aromatic rings. |
| WOS关键词 | C-H ACTIVATION ; N BOND FORMATION ; O-METHYL OXIMES ; INTERNAL ALKYNES ; ROOM-TEMPERATURE ; PROTECTED ARYLAMINES ; SULFONYL AZIDES ; MILD CONDITIONS ; DIAZO-COMPOUNDS ; BENZOIC-ACIDS |
| 资助项目 | National Natural Science Foundation of China[21302200] |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000335197000028 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| 源URL | [http://119.78.100.183/handle/2S10ELR8/277081]  |
| 专题 | 药物化学研究室 |
| 通讯作者 | Li, Yuanchao |
| 作者单位 | Chinese Acad Sci, Shanghai Inst Mat Med, Shanghai 201203, Peoples R China |
| 推荐引用方式 GB/T 7714 | Du, Juanjuan,Yang, Yaxi,Feng, Huijin,et al. Rhodium- Catalyzed Direct Amination of Arenes with Nitrosobenzenes: A New Route to Diarylamines[J]. CHEMISTRY-A EUROPEAN JOURNAL,2014,20(19):5727-5731. |
| APA | Du, Juanjuan,Yang, Yaxi,Feng, Huijin,Li, Yuanchao,&Zhou, Bing.(2014).Rhodium- Catalyzed Direct Amination of Arenes with Nitrosobenzenes: A New Route to Diarylamines.CHEMISTRY-A EUROPEAN JOURNAL,20(19),5727-5731. |
| MLA | Du, Juanjuan,et al."Rhodium- Catalyzed Direct Amination of Arenes with Nitrosobenzenes: A New Route to Diarylamines".CHEMISTRY-A EUROPEAN JOURNAL 20.19(2014):5727-5731. |
入库方式： OAI收割
来源：上海药物研究所
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