Rhodium-Catalyzed Highly Enantioselective Addition of Arylboronic Acids to Cyclic Aldimines: Practical Asymmetric Synthesis of Cyclic Sulfamidates
文献类型：期刊论文
| 作者 | Wang, Hui; Xu, Ming-Hua
|
| 刊名 | SYNTHESIS-STUTTGART
 |
| 出版日期 | 2013-08 |
| 卷号 | 45期号:15页码:2125-2133 |
| 关键词 | asymmetric catalysis cyclization arylation rhodium boron ligands sulfamidates heterocycles |
| ISSN号 | 0039-7881 |
| DOI | 10.1055/s-0033-1338418 |
| 文献子类 | Article |
| 英文摘要 | A highly efficient asymmetric arylation of cyclic N-sulfonyl aldimines with arylboronic acids catalyzed by a rhodium/sulfur-olefin ligand complex under mild conditions is described. A wide range 4-aryl-3,4-dihydro-1,2,3-benzoxathiazine 2,2-dioxides were obtained in extremely high yields (93-99%) and high enantiomeric purities (97-99% ee). |
| WOS关键词 | SULFUR-OLEFIN LIGANDS ; H BOND OXIDATION ; SULFAMATE ESTERS ; NUCLEOPHILIC DISPLACEMENTS ; INTRAMOLECULAR AMIDATION ; RUTHENIUM PORPHYRINS ; SULFONAMIDE MOIETIES ; CONJUGATE ADDITIONS ; AMINE DERIVATIVES ; ALPHA-KETOESTERS |
| 资助项目 | National Natural Science Foundation of China[20972172] ; National Natural Science Foundation of China[21021063] |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000322065900015 |
| 出版者 | GEORG THIEME VERLAG KG |
| 源URL | [http://119.78.100.183/handle/2S10ELR8/277525]  |
| 专题 | 药物化学研究室 |
| 通讯作者 | Xu, Ming-Hua |
| 作者单位 | Chinese Acad Sci, Shanghai Inst Mat Med, Shanghai 201203, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wang, Hui,Xu, Ming-Hua. Rhodium-Catalyzed Highly Enantioselective Addition of Arylboronic Acids to Cyclic Aldimines: Practical Asymmetric Synthesis of Cyclic Sulfamidates[J]. SYNTHESIS-STUTTGART,2013,45(15):2125-2133. |
| APA | Wang, Hui,&Xu, Ming-Hua.(2013).Rhodium-Catalyzed Highly Enantioselective Addition of Arylboronic Acids to Cyclic Aldimines: Practical Asymmetric Synthesis of Cyclic Sulfamidates.SYNTHESIS-STUTTGART,45(15),2125-2133. |
| MLA | Wang, Hui,et al."Rhodium-Catalyzed Highly Enantioselective Addition of Arylboronic Acids to Cyclic Aldimines: Practical Asymmetric Synthesis of Cyclic Sulfamidates".SYNTHESIS-STUTTGART 45.15(2013):2125-2133. |
入库方式： OAI收割
来源：上海药物研究所
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