Chiral Sulfinamide-Olefin Ligands: Switchable Selectivity in Rhodium-Catalyzed Asymmetric 1,2-Addition of Arylboronic Acids to Aliphatic -Ketoesters
文献类型：期刊论文
| 作者 | Zhu, Ting-Shun; Xu, Ming-Hua
|
| 刊名 | CHINESE JOURNAL OF CHEMISTRY
 |
| 出版日期 | 2013-03 |
| 卷号 | 31期号:3页码:321-328 |
| 关键词 | asymmetric catalysis rhodium sulfur-olefin ligand 1 2-addition stereoselectivity reversal |
| ISSN号 | 1001-604X |
| DOI | 10.1002/cjoc.201300063 |
| 文献子类 | Article |
| 英文摘要 | Simple and readily available chiral N-(sulfinyl)allylamines have been developed as efficient novel ligands for the rhodium-catalyzed enantioselective 1,2-addition of arylboronic acids to challenging aliphatic -ketoesters. By employing the linear or branched sulfinamide-olefin ligands, interesting enantioselectivity as well as regioselectivity reversal in the related asymmetric additions were observed. |
| WOS关键词 | ARYL BORONIC ACIDS ; ALPHA-KETOESTERS ; ALPHA,BETA-UNSATURATED KETONES ; ENANTIOSELECTIVE 1,2-ADDITION ; ADDITION-REACTIONS ; HYDROXYLATION ; ALDEHYDES ; PALLADACYCLES ; 1,2-DIKETONES ; 1,4-ADDITION |
| 资助项目 | National Natural Science Foundation of China[20972172] ; National Natural Science Foundation of China[21021063] |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| CSCD记录号 | CSCD:4793359 |
| WOS记录号 | WOS:000316809600005 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| 源URL | [http://119.78.100.183/handle/2S10ELR8/277706]  |
| 专题 | 药物化学研究室 |
| 通讯作者 | Xu, Ming-Hua |
| 作者单位 | Chinese Acad Sci, Shanghai Inst Mat Med, Shanghai 201203, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhu, Ting-Shun,Xu, Ming-Hua. Chiral Sulfinamide-Olefin Ligands: Switchable Selectivity in Rhodium-Catalyzed Asymmetric 1,2-Addition of Arylboronic Acids to Aliphatic -Ketoesters[J]. CHINESE JOURNAL OF CHEMISTRY,2013,31(3):321-328. |
| APA | Zhu, Ting-Shun,&Xu, Ming-Hua.(2013).Chiral Sulfinamide-Olefin Ligands: Switchable Selectivity in Rhodium-Catalyzed Asymmetric 1,2-Addition of Arylboronic Acids to Aliphatic -Ketoesters.CHINESE JOURNAL OF CHEMISTRY,31(3),321-328. |
| MLA | Zhu, Ting-Shun,et al."Chiral Sulfinamide-Olefin Ligands: Switchable Selectivity in Rhodium-Catalyzed Asymmetric 1,2-Addition of Arylboronic Acids to Aliphatic -Ketoesters".CHINESE JOURNAL OF CHEMISTRY 31.3(2013):321-328. |
入库方式： OAI收割
来源：上海药物研究所
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