Development of Bicyclo[3.3.0]octadiene-or Dicyclopentadiene-Based Chiral Diene Ligands for Transition-Metal-Catalyzed Reactions
文献类型：期刊论文
| 作者 | Feng, Chen-Guo1; Xu, Ming-Hua1,2 ; Lin, Guo-Qiang1
|
| 刊名 | SYNLETT
 |
| 出版日期 | 2011-06 |
| 期号 | 10页码:1345-1356 |
| 关键词 | asymmetric catalysis diene complexes Michael additions cross-coupling rhodium |
| ISSN号 | 0936-5214 |
| DOI | 10.1055/s-0030-1260572 |
| 文献子类 | Article |
| 英文摘要 | This account summarizes our efforts on the design, synthesis, and application of two classes of chiral diene ligands bearing bicyclo[3.3.0] octadiene or dicyclopentadiene skeletons. These chiral diene ligands can be readily prepared from inexpensive commercial materials with enzymatic resolution as the key synthetic step. The ligands have been successfully applied in some rhodium-catalyzed reactions, including 1,4-addition to alpha, beta-unsaturated carbonyl compounds, arylation of imines, and conjugate addition to nitroalkenes. In addition, they have been used in the first successful palladium-diene-catalyzed asymmetric reaction. |
| WOS关键词 | ENANTIOSELECTIVE CONJUGATE ADDITION ; ELECTRON-DEFICIENT OLEFINS ; MIYAURA COUPLING REACTION ; HIGHLY EFFICIENT LIGANDS ; ARYLBORONIC ACIDS ; ASYMMETRIC 1,4-ADDITION ; N-TOSYLARYLIMINES ; BORONIC ACIDS ; PALLADIUM COMPLEXES ; ORGANOBORONIC ACIDS |
| 资助项目 | National Natural Science Foundation of China[21002112] ; Major State Basic Research Development Program[2010CB833302] ; Shanghai Municipal Committee of Science and Technology[09JC1417300] |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000291306800003 |
| 出版者 | GEORG THIEME VERLAG KG |
| 源URL | [http://119.78.100.183/handle/2S10ELR8/278517]  |
| 专题 | 药物化学研究室 |
| 通讯作者 | Lin, Guo-Qiang |
| 作者单位 | 1.Chinese Acad Sci, Shanghai Inst Organ Chem, Key Lab Synthet Chem Nat Subst, Shanghai 200032, Peoples R China; 2.Chinese Acad Sci, Shanghai Inst Mat Med, Shanghai 201203, Peoples R China |
| 推荐引用方式 GB/T 7714 | Feng, Chen-Guo,Xu, Ming-Hua,Lin, Guo-Qiang. Development of Bicyclo[3.3.0]octadiene-or Dicyclopentadiene-Based Chiral Diene Ligands for Transition-Metal-Catalyzed Reactions[J]. SYNLETT,2011(10):1345-1356. |
| APA | Feng, Chen-Guo,Xu, Ming-Hua,&Lin, Guo-Qiang.(2011).Development of Bicyclo[3.3.0]octadiene-or Dicyclopentadiene-Based Chiral Diene Ligands for Transition-Metal-Catalyzed Reactions.SYNLETT(10),1345-1356. |
| MLA | Feng, Chen-Guo,et al."Development of Bicyclo[3.3.0]octadiene-or Dicyclopentadiene-Based Chiral Diene Ligands for Transition-Metal-Catalyzed Reactions".SYNLETT .10(2011):1345-1356. |
入库方式： OAI收割
来源：上海药物研究所
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